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重要文件

M11103

Sigma-Aldrich

4-甲氧基苄胺

98%

同義詞:

1-氨甲基-4-甲氧基苯, 4-甲氧基苯甲胺, 对甲氧基苄胺, 山莨菪碱, (4-甲氧基苯基)甲胺, (对甲氧基苯基)甲胺

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About This Item

線性公式:
CH3OC6H4CH2NH2
CAS號碼:
分子量::
137.18
Beilstein:
508206
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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品質等級

化驗

98%

形狀

liquid

折射率

n20/D 1.546 (lit.)

bp

236-237 °C (lit.)

密度

1.05 g/mL at 25 °C (lit.)

SMILES 字串

COc1ccc(CN)cc1

InChI

1S/C8H11NO/c1-10-8-4-2-7(6-9)3-5-8/h2-5H,6,9H2,1H3

InChI 密鑰

IDPURXSQCKYKIJ-UHFFFAOYSA-N

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應用

4-甲氧基苄胺属于一级胺,可用于:
  • 官能化芳基溴的胺化反应。[1]
  • 合成体内应用的官能化有机聚磷腈。[2]
  • 合成具有抗增殖活性的肌球蛋白、8-氮杂嘌呤类似物。[3]
  • 研究2-硝基-和2,4-二硝基苯磺酰胺等氨基保护基团的脱保护步骤。[4]

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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分析證明 (COA)

Lot/Batch Number

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T Jonsson et al.
Biochemistry, 33(49), 14871-14878 (1994-12-13)
Competitive kH/kT and kD/kT kinetic isotope effects on p-methoxybenzylamine oxidation by the 8 alpha-S-cysteinyl flavin adenine dinucleotide (FAD)-dependent enzyme monoamine oxidase B (MAO-B) have been measured as a function of temperature. At pH 7.5, exponents relating observed kH/kT and kD/kT
2-Nitro-and 2, 4-dinitrobenzenesulfonamides as protecting groups for primary amines.
Nihei KI, et al.
Synlett, 2001(07), 1167-1169 (2001)
Synthesis and biological activity of 8-azapurine and pyrazolo [4, 3-d] pyrimidine analogues of myoseverin.
Krystof V, et al.
European Journal of Medicinal Chemistry, 41(12), 1405-1411 (2006)
Anna Berlicka et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 9(10), 1359-1366 (2010-09-08)
A variety of primary and secondary benzylic amines were oxidized efficiently to N-benzylidenebenzylamines and imines, respectively, using 2,7,12,17-tetrapropylporphycene (H(2)TPrPc) photocatalyst and blue light emitting diodes (LEDs). The photooxidation of 4-methoxybenzylamine in the presence of H(2)TPrPc and its tin(IV) complex Sn(TPrPc)Cl(2)
Synthesis and characterization of novel polyorganophosphazenes substituted with 4-methoxybenzylamine and 4-methoxyphenethylamine for in vitro release of indomethacin and 5-fluorouracil.
Gudasi KB, et al.
Reactive and Functional Polymers, 66(10), 1149-1157 (2006)

Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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