推薦產品
![(3AR,5S,6S,6AR)-5-((R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL)-2,2-DIMETHYLTETRAHYDROFURO[3,2-D][1,3]DIOXOL-6-OL AldrichCPR](/deepweb/assets/sigmaaldrich/product/structures/241/825/1c695a85-5c36-42d3-806a-30876a4dabac/640/1c695a85-5c36-42d3-806a-30876a4dabac.png)
品質等級
化驗
98%
形狀
powder
光學活性
[α]20/D −18°, c = 1% in H2O
mp
109-113 °C (lit.)
SMILES 字串
[H][C@@]1(O[C@H]2O[C@@H](O[C@@H]2[C@H]1O)C(Cl)(Cl)Cl)[C@H]3COC(C)(C)O3
InChI
1S/C12H20O6/c1-11(2)14-5-6(16-11)8-7(13)9-10(15-8)18-12(3,4)17-9/h6-10,13H,5H2,1-4H3/t6-,7+,8-,9-,10-/m1/s1
InChI 密鑰
KEJGAYKWRDILTF-JDDHQFAOSA-N
應用
1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose can be used as a starting material to prepare:
- Biologically active L-acovenose, 6-deoxy-L-idose[1] and, carbanucleoside enantiomers.[2]
- Vinyl ether-based chiral carbohydrate synthon by reacting with acetylene using superbase catalytic systems.[3]
- Fluoro-thiofuranosyl nucleosides of biological importance.[4]
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 2
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
客戶也查看了
Direct vinylation of glucose derivatives with acetylene
Trofimov BA, et al.
Tetrahedron, 63(47), 11661-11665 (2007)
An efficient synthesis of 3-fluoro-5-thio-xylofuranosyl nucleosides of thymine, uracil, and 5-fluorouracil as potential antitumor or/and antiviral agents
Tsoukala E, et al.
Bioorganic & Medicinal Chemistry, 15(9), 3241-3247 (2007)
Guylaine M Defossemont et al.
Carbohydrate research, 338(6), 563-565 (2003-04-02)
The synthesis and characterisation of a novel chiral bicyclic oxacaprolactone is reported. The choice of diisopropylidene-D-glucose as a starting material allowed selective introduction of the synthetic equivalent necessary for the formation of the seven-membered ring of the lactone, i.e., one
S C Hung et al.
Carbohydrate research, 331(4), 369-374 (2001-06-12)
A practical route toward the synthesis of 6-deoxy-L-idose and L-acovenose from 1,2:5,6-di-O-isopropylidene-alpha-D-glucofuranose is described. Key steps include the stereoselective hydrogenation of 6-deoxy-1,2:3,5-di-O-isopropylidene-alpha-D-xylo-hex-5-enofuranose, regioselective protection of 6-deoxy-1,2-O-isopropylidene-beta-L-idofuranose at 0-5, and epimerisation of 6-deoxy-5-O-tert-butyldimethylsilyl-1,2-O-isopropylidene-beta-L-idofuranose at C-3.
Z Huang et al.
Methods in molecular biology (Clifton, N.J.), 20, 315-353 (1993-01-01)
Two sets of experimental protocols are given for the synthesis of 3',5'-bis-homodeoxyribonucleosides, building blocks for the synthesis of oligodeoxynucleotide analogs where the -O-PO2-O- groups are replaced by -CH2-S-CH2-, -CH2-SO-CH2-, and -CH2-SO2-CH2- units. Conditions are presented for joining these building blocks
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