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重要文件

C91492

Sigma-Aldrich

溴化氰

reagent grade, 97%

同義詞:

氰化溴

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About This Item

線性公式:
BrCN
CAS號碼:
分子量::
105.92
Beilstein:
1697296
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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等級

reagent grade

蒸汽密度

3.65 (vs air)

蒸汽壓力

100 mmHg ( 22.6 °C)

化驗

97%

形狀

crystals

bp

61-62 °C (lit.)

mp

50-53 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

BrC#N

InChI

1S/CBrN/c2-1-3

InChI 密鑰

ATDGTVJJHBUTRL-UHFFFAOYSA-N

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一般說明

Cyanogen bromide (CNBr) is a halogen halide. Its utility as a condensing agent during chemical ligation of oligodeoxyribonucleotides has been reported.[1] Its threshold photoelectron (TPE) spectrum has been recorded under high resolution.[2] The cryopolymerization of CNBr on irradiation has been investigated.[3]

應用

用于肽的断裂[4]和用于蛋白质固化过程。[5]与 C60Ph5Cl 反应生成新型苯代异喹啉并[3′,4′:1,2][60]富勒烯。[6]
Cyanogen bromide may be used:
  • To activate polysaccharides for coupling with erythrocytes.[7]
  • As an oxidizing agent in urine thaimine assay.[8]
  • In the preparation of 2-amino-5-(2′-thienyl)-1,3,4-oxadiazole.[9]

訊號詞

Danger

危險分類

Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Eye Dam. 1 - Skin Corr. 1B

安全危害

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

>149.0 °F - closed cup

閃點(°C)

> 65 °C - closed cup

個人防護裝備

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges


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分析證明 (COA)

Lot/Batch Number

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Applied Biochemistry and Biotechnology, 44, 135-135 (1994)
Org. Mass Spectrom., 28, 1395-1395 (1993)
N I Sokolova et al.
FEBS letters, 232(1), 153-155 (1988-05-09)
Cyanogen bromide was found to condense oligodeoxyribonucleotides on a complementary template in aqueous solution. Optimum conditions for this vigorous and effective reaction were developed. CNBr proved to be useful for incorporation of phosphoramidate or pyrophosphate internucleotide bonds in DNA duplexes.
Abdul-Sada, A.K. et al.
Chemical Communications (Cambridge, England), 307-307 (1998)
Threshold photoelectron spectroscopy of cyanogen bromide.
Yencha AJ, et al.
Chemical Physics Letters, 392(1), 202-208 (2004)

Questions

1–3 of 3 Questions  
  1. Hi, is this sterile and suitable for cell culture? Thank you.

    1 answer
    1. This product is not sterile and has not been tested for cell culture applications. Therefore, it may not be suitable for use in cell culture without proper sterilization procedures.

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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