927783

XPhos Pd G3 ChemBeads

• 同義詞: (2-Dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate, XPhos-G3-Palladacycle, XPhos-Pd-G3
• 經驗公式（希爾表示法）: C₄₆H₆₂NO₃PPdS
• CAS號碼: 1445085-55-1
• 分子量：: 846.45
• MDL號碼: MFCD22666043
• 分類程式碼代碼: 12352101
• NACRES: NA.82

屬性

• 形狀: solid
• 品質等級: 100
• 成份: ~ 4 wt.% loading of catalyst
• 反應適用性: reagent type: catalyst; reaction type: Cross Couplings
• SMILES 字串: [Pd](O[S](=O)(=O)C)c5c(cccc5)c6c(cccc6)N.P(C4CCCCC4)(C3CCCCC3)c1c(cccc1)c2c(cc(cc2C(C)C)C(C)C)C(C)C
• InChI 密鑰: NKKHABPORDUWIG-UHFFFAOYSA-M

描述

一般說明

XPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. XPhos Pd G3 is an excellent reagent for Suzuki cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

For larger scale uses, product also available in powdered form (763381)

應用

XPhos Pd G3 may be used in the following reactions:

• Cyanation reaction of heterocyclic halides.
• Coupling of heteroaryl chlorides with polyfluoroaryl zinc reagents.
• Coupling of 2,6-difluorophenylboronic acid with (hetero)aryl chlorides.

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
Learn more about ChemBeads products

其他說明

High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads

Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation

ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

安全資訊

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3