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重要文件

903191

Sigma-Aldrich

Benzyl 4-oxo-5-(triethylsilyl)-3,4-dihydropyridine-1(2H)-carboxylate

同義詞:

Garg silyl triflate precursor

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About This Item

經驗公式(希爾表示法):
C19H27NO3Si
CAS號碼:
分子量::
345.51
分類程式碼代碼:
12352005
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形狀

liquid

折射率

n/D 1.548

密度

1.079 g/mL

官能基

ketone
phenyl

儲存溫度

−20°C

應用

Benzyl 4-oxo-5-(triethylsilyl)-3,4-dihydropyridine-1(2H)-carboxylate is a precursor to a Garg silyl triflate which upon exposure to fluoride generates a reactive azacyclic allene for cycloaddition reactions.

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3


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分析證明 (COA)

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Joyann S Barber et al.
Nature chemistry, 10(9), 953-960 (2018-08-01)
For over a century, the structures and reactivities of strained organic compounds have captivated the chemical community. Whereas triple-bond-containing strained intermediates have been well studied, cyclic allenes have received far less attention. Additionally, studies of cyclic allenes that bear heteroatoms

相關內容

The Garg group develops methods for the synthesis of natural products and pharmaceuticals. One key method pertains to heterocyclic arynes, such as indolynes and pyridynes, which are generated in situ from silyltriflate precursors under mild fluoride based reaction conditions.

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