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重要文件

901223

Sigma-Aldrich

3-(Trimethylsilyl)propargyl methacrylate

≥98.0%, contains 200 ppm MEHQ as inhibitor

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About This Item

經驗公式(希爾表示法):
C10H16O2Si
CAS號碼:
分子量::
196.32
MDL號碼:
分類程式碼代碼:
12162002
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化驗

≥98.0%

形狀

liquid

包含

200 ppm MEHQ as inhibitor

顏色

colorless to pale yellow

運輸包裝

wet ice

儲存溫度

−20°C

一般說明

3-(Trimethylsilyl)propargyl methacrylate is a methacrylate-based monomer for use in the synthesis of alkyne-functionalized polymers and copolymers. The incorporation of alkynes allows for rapid post-polymerization modification through reactions, such as copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) or thiol-yne click reactions. These reactions are highly preferable for functionalization due their high efficiency and the ability to easily install the corresponding functionality (e.g., azides or thiols) onto the biomolecule or small molecule of interest. While alkynes offer great promise for post-polymerization functionalization, it is difficult to polymerize bifunctional, alkyne-containing monomers without the synthesis of branched or highly gelled products. 3-(Trimethylsilyl)propargyl methacrylate features a silyl-protected alkyne that can be easily deprotected post-polymerization to yield alkyne-functionalized polymers and copolymers.

象形圖

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訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

193.1 °F

閃點(°C)

89.5 °C


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Graft block copolymers of propargyl methacrylate and vinyl acetate via a combination of RAFT/MADIX and click chemistry: Reaction analysis.
Quemener, D. et al
Journal of Polymer Science Part A: Polymer Chemistry, 46, 155-173 (2008)
Clickable initiators, monomers and polymers in controlled radical polymerizations?a prospective combination in polymer science.
Mansfeld, U. et al
Polym. Chem., 1, 1560-1598 (2010)
Vincent Ladmiral et al.
Journal of the American Chemical Society, 128(14), 4823-4830 (2006-04-06)
The synthesis of novel well-defined alkyne side chain functional polymers featuring narrow molecular weight distributions (PDI = 1.09-1.17) by living radical polymerization is described. Grafting of protected and unprotected carbohydrates is achieved via either a C-6 or an anomeric azide

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