901062

Pinacol (dichloromethyl) boronate

≥95%

• 同義詞: 1,3,2-Dioxaborolane, 2-(dichloromethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, Dichloromethyl pinacol boronate
• 經驗公式（希爾表示法）: C₇H₁₃BCl₂O₂
• CAS號碼: 83622-41-7
• 分子量：: 210.89
• MDL號碼: MFCD27976342
• 分類程式碼代碼: 12352200
• NACRES: NA.22

屬性

• 品質等級: 100
• 化驗: ≥95%
• 形狀: (Powder or Solid or Crystals or Semi-Solid or Liquid)
• 折射率: n/D 1.4511
• 密度: 1.1423
• 官能基: chloro
• SMILES 字串: B1(OC(C(O1)(C)C)(C)C)C(Cl)Cl
• InChI: 1S/C7H13BCl2O2/c1-6(2)7(3,4)12-8(11-6)5(9)10/h5H,1-4H3
• InChI 密鑰: GQFQFYFLABSDDS-UHFFFAOYSA-N

描述

應用

Pinacol (dichloromethyl) boronate is a general reagent that was employed by Prof. Greg C. Fu and coworkers to achieve the iterative synthesis of asymmetric (secondary) alkyl boronate esters. These can be further derivatized through a growing suite of chemical transformations developed in the last decade (cross coupling, oxidation, amination, halogenation) that proceed with stereochemical fidelity.

其他說明

A general, modular method for the catalytic asymmetric synthesis of alkylboronate esters

安全資訊

• 儲存類別代碼: 10 - Combustible liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 201.2 °F
• 閃點（°C）: 94 °C