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重要文件

323136

Sigma-Aldrich

三甲基硼氧六环

99%

同義詞:

2,4,6-Trimethyl-1,3,5,2,4,6-trioxatriborinane, 2,4,6-Trimethylboroxine, Methaneboronic anhydride, Trimethyl-1,3,5,2,4,6-trioxatriborinane

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About This Item

經驗公式(希爾表示法):
C3H9B3O3
CAS號碼:
分子量::
125.53
Beilstein:
1757008
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22
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品質等級

化驗

99%

形狀

liquid

折射率

n20/D 1.362 (lit.)

bp

78-80 °C (lit.)

mp

−38 °C (lit.)

密度

0.898 g/mL at 25 °C (lit.)

SMILES 字串

Cb1ob(C)ob(C)o1

InChI

1S/C3H9B3O3/c1-4-7-5(2)9-6(3)8-4/h1-3H3

InChI 密鑰

GBBSAMQTQCPOBF-UHFFFAOYSA-N

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應用

三甲基环三硼氧烷(TMB)是一种由甲基硼酸构成的环酐。它可用于:
  • 作为气相色谱/质谱分析的衍生剂。[1]
  • 制备甲基铝氧烷(MAO),用于烯烃的聚合。[2]
  • 作为电解质添加剂,提高电极/电解质的界面稳定性。[3]
  • 通过钯催化suzuki - miyura偶联反应甲基化芳基卤化物。[4]
  • 制备CBS(Corey、Bakshi和Shibata)催化剂,以不对称还原酮成醇。[5]

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FlameCorrosion

訊號詞

Danger

危險聲明

危險分類

Flam. Liq. 2 - Skin Corr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

15.8 °F - closed cup

閃點(°C)

-9 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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存取文件庫

Reactivity of metallocene catalysts for olefin polymerization: influence of activator nature and structure
Pedeutour JN
Macromolecular Rapid Communications, 22(14), 1095-1123 (2001)
Tetrahedron Asymmetry, 14, 2115-2118 (2003)
Polymer, 37, 4629-4629 (1996)
Enhanced high voltage performances of layered lithium nickel cobalt manganese oxide cathode by using trimethylboroxine as electrolyte additive
Yu Q, et al.
Electrochimica Acta, 176(14), 919-925 (2015)
Practical methylation of aryl halides by Suzuki-Miyaura coupling.
Gray M, et al.
Tetrahedron Letters, 41(32), 6237-6240 (2000)

Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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