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805203

Sigma-Aldrich

FK 102 Co (III) TFSI 盐

同義詞:

三(2-(1H-吡唑-1-基）吡啶）三（双（三氟甲烷）磺酰亚胺）钴（III）

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About This Item

經驗公式（希爾表示法）:
C30H21CoN12O12S6F18
分子量：:
1334.86
分類程式碼代碼:
12352103
PubChem物質ID:
329768920
NACRES:
NA.23

化驗

98%

品質等級

100

形狀

powder

mp

194-199 °C

SMILES 字串

O=S([N-]S(=O)(C(F)(F)F)=O)(C(F)(F)F)=O.O=S([N-]S(=O)(C(F)(F)F)=O)(C(F)(F)F)=O.O=S([N-]S(=O)(C(F)(F)F)=O)(C(F)(F)F)=O.N1(C2=NC=CC=C2)N=CC=C1.C3(N4C=CC=N4)=CC=CC=N3.C5(N6C=CC=N6)=CC=CC=N5.[Co+3]

InChI

1S/3C8H7N3.3C2F6NO4S2.Co/c3*1-2-5-9-8(4-1)11-7-3-6-10-11;3*3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/h3*1-7H;;;;/q;;;3*-1;+3

InChI 密鑰

ILXRZLQXWLMDFQ-UHFFFAOYSA-N

相關類別

一般說明

FK 102 Co（III）TFSI盐是一种钴（III）配合物，可以用作p型掺杂剂，以控制有机和无机半导体中载流子的类型和密度。TFSI的溶解度可以增加电化学装置中空穴导体的掺杂电势。

應用

FK 102 Co（III）TFSI盐可主要用于制造染料敏化太阳能电池（DSSC）和钙钛矿基太阳能电池（PSC）。
用这种钴配合物大幅度提高液体电解质电池的光电压，或通过固态光伏器件实现超高性能。FK102钴配合物可提供有保证的性能、高重现性、一致的结果，并且具有最高的纯度。与基于三碘化物的氧化还原电解质相比，钴配合物通常可增加光电压，尤其是在较低的光照水平下（例如，在室内应用），从而显著提高设备的功率输出。
推荐用于：
在液基电解液中：通常为0.15-0.2 M的Co（II）和约0.05 M 的Co（II）
在固态光伏电池中：添加至空穴传输材料系统中，重量百分比不超过10％。

法律資訊

Greatcell Solar Materials Pty Ltd. 的产品。Greatcell Solar是Greatcell Solar Materials Pty Ltd.的注册商标。

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

分析證明 (COA)

輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號，寫有 ‘Lot’或‘Batch’.。

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Planar heterojunction perovskite solar cell based on CdS electron transport layer
Abulikemu M, et al.
Thin Solid Films, 636(37), 512-518 (2017)
Cooperative tin oxide fullerene electron selective layers for high-performance planar perovskite solar cells
Ke W, et al.
Journal of Material Chemistry A, 4(37), 14276-14283 (2016)
Co (III) complexes as p-dopants in solid-state dye-sensitized solar cells
Burschka J, et al.
Chemistry of Materials, 25(15), 2986-2990 (2013)
B P MacLeod et al.
Science advances, 6(20), eaaz8867-eaaz8867 (2020-05-20)
Discovering and optimizing commercially viable materials for clean energy applications typically takes more than a decade. Self-driving laboratories that iteratively design, execute, and learn from materials science experiments in a fully autonomous loop present an opportunity to accelerate this research
Julian Burschka et al.
Nature, 499(7458), 316-319 (2013-07-12)
Following pioneering work, solution-processable organic-inorganic hybrid perovskites-such as CH3NH3PbX3 (X = Cl, Br, I)-have attracted attention as light-harvesting materials for mesoscopic solar cells. So far, the perovskite pigment has been deposited in a single step onto mesoporous metal oxide films
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