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684449

Sigma-Aldrich

[6,6]-苯基 C 61 丁酸甲酯

≥99%

同義詞:

1-[3-(甲氧羰基)丙基]-1-苯基-[6.6]C61, 3′H-环丙[1,9] [5,6]富勒烯-C60-Ih-3′-丁酸 3′-苯甲酯, PCBM, [60]PCBM

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About This Item

經驗公式（希爾表示法）:
C72H14O2
CAS號碼:
160848-22-6
分子量：:
910.88
MDL號碼:
MFCD07784544
分類程式碼代碼:
12352103
PubChem物質ID:
24885805
NACRES:
NA.23
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描述

functionalized fullerene

品質等級

100

化驗

≥99%

形狀

solid

軌道能量

HOMO 6.1 eV 
LUMO 3.7 eV 

半導體屬性

N-type (mobility=0.21 cm2/V·s)

SMILES 字串

COC(=O)CCCC2(c1ccccc1)[C]3=4c5c6c7c8c9c%10c(c%11c%12c3c%13c5c%14c%15c6c%16c7c%17c9c%18c%19c%10c%20c%11c%21c%12c%22c%13c%23c%14c%24c%15c%25c%16c%26c%17c%18c%27c%28c%19c%20c%29c%21c%30c%22c%23c%31c%24c%32c%25c%26c%27c%33c%28c%29c%30c%31c%32%33)[C]2=48

InChI

1S/C72H14O2/c1-74-11(73)8-5-9-70(10-6-3-2-4-7-10)71-66-59-52-40-32-23-14-12-13-15-18(14)27-34(32)42-43-35(27)33-24(15)26-22-17(13)20-19-16(12)21-25(23)38(40)46-44-30(21)28(19)36-37-29(20)31(22)45-47-39(26)41(33)53-55(43)64(63(66)54(42)52)67-60(53)58(47)62-51(45)49(37)56-48(36)50(44)61(57(46)59)68(71)65(56)69(62)72(67,70)71/h2-4,6-7H,5,8-9H2,1H3

InChI 密鑰

MCEWYIDBDVPMES-UHFFFAOYSA-N

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相關類別

一般說明

[6,6]-苯基C61丁酸甲酯（[60] PCBM）是一种甲基富勒烯，其在有机分子中的扩散能力优于比富勒烯（C60）。它具有很高的电子迁移率，因此可以在主要的电化学应用中用作电子受体。[1][2]
（6,6）-苯基C61丁酸甲酯（（60）PCBM）是一种甲基富勒烯，其在有机分子中的扩散能力优于比富勒烯（C60）。它具有很高的电子迁移率，因此可以在主要的电化学应用中用作电子受体。 [1][2]

應用

[60] PCBM是一种具有低成本和高表面积的n型半导体。它被广泛用作各种基于能量的应用中的电子传输材料，例如有机光伏，[3][4] 钙钛矿太阳能电池[5][6] 场效应晶体管[7][8] 和光电探测器。[9]
可溶 n-沟道有机半导体。在塑料电子学中用作 n 型层，特别是体异质结 OFET 和光伏电池 (PV)。
（60）PCBM是一种n型半导体，广泛用作电子传输材料，具有低成本和高表面积，可用于不同的基于能量的应用，例如有机光伏）、[3][4] 钙钛矿太阳能电池[5][6]、场效应晶体管[7][8] 和光电探测器。[9]

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)

從最近期的版本中選擇一個：

分析證明 (COA)

Lot/Batch Number
MKCW7362
MKCW5498
WXBF4613V
MKCT2660
MKCS9314

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存取文件庫

Independent control of open-circuit voltage of organic solar cells by changing film thickness of MoO3 buffer layer
Kinoshita, Y.; Takenaka, R.; Murata, H.
Applied Physics Letters, 92, 243309-243309 (2008)
Efficient and highly air stable planar inverted Perovskite solar cells with reduced Graphene oxide doped PCBM electron transporting layer.
Kakavelakis G, et al.
Advanced Energy Materials, 7(7), 1602120-1602120 (2017)
Improving the photo current of the (60) PCBM/P3HT photodetector device by using wavelength-matched photonic crystals.
Li S, et al.
Journal of Material Chemistry C, 2(8), 1500-1504 (2014)
Field-effect transistor structures on the basis of poly (3-hexylthiophene), fullerene derivatives (60) PCBM,(70) PCBM, and nickel nanoparticles.
Aleshin N, et al.
Physics of the Solid State, 58(9), 1882-1890 (2016)
First-principles investigation of organic photovoltaic materials C 60, C 70,(C 60) PCBM, and bis-(C 60) PCBM using a many-body G 0 W 0-Lanczos approach.
Qian X, et al.
Physical Review. B, Condensed Matter and Materials Physics, 91(24), 245105-245105 (2015)
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PCBM-Based n-Type Semiconductors

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基于PCBM的n型半导体

基于PCBM的n型半导体 - 根据PCBM库和性质查找可用的p型和n型有机半导体。

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Questions

1–3 of 3 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. Please let me know its absorbance maxima wavelength.

    1 answer

    1. 684449 is a [6,6]-Phenyl C61 butyric acid methyl ester. Unfortunately, the max absorbance wavelength is not tested.

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