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449504

Sigma-Aldrich

双(三氟甲烷)磺酰亚胺 锂盐

同義詞:

双(三氟甲基磺酰)胺 锂盐, 双三氟甲烷磺酰亚胺锂

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About This Item

線性公式:
CF3SO2NLiSO2CF3
CAS號碼:
分子量::
287.09
Beilstein:
6625414
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.22
暫時無法取得訂價和供貨情況

mp

234-238 °C (lit.)

官能基

fluoro

SMILES 字串

[Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F

InChI

1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1

InChI 密鑰

QSZMZKBZAYQGRS-UHFFFAOYSA-N

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相關類別

應用

双(三氟甲烷)磺酰亚胺锂盐(Li-TFSI)可用于:
  • 用作提高卟啉基有机太阳能电池电力转换效率的化学添加剂。[1]     
  • 用作制备含咪唑核心单体离子液体的试剂,以开发聚合离子液体。[2]
  • 通过相应三氟甲磺酸酯的阴离子复分解,制备手性咪唑鎓盐。[3]       
  • 合成用于锂离子电池的固体聚合物电解质。[4][5] 
  • 合成聚电解质可重复使用均相催化剂,可用于异戊二烯和各种亲二烯体间的Diels-Alder反应。[6]
  • 用于制备锂电池电解液[7][8][9]和新型稀土路易斯酸催化剂。[10]

其他說明

关于含氟氮酸的综述,请参见 Coordination Chemistry Reviews。[11]

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Oral

標靶器官

Nervous system

儲存類別代碼

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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An appraisal of tetraethylsulfamide as plasticizer for poly (ethylene oxide)- LiN (CF3SO2)2 rubbery electrolytes
Labreche C, et al.
Macromolecules, 29, 7795-7795 (1996)
C Roux et al.
Journal of physics. Condensed matter : an Institute of Physics journal, 8(38), 7005-7017 (1999-01-01)
The physical properties of the ionic conductor [Formula: see text], obtained by dissolution of lithium trifluoromethanesulphonylimide in poly(propylene oxide), have been investigated for several values of n. The glass transition temperature [Formula: see text] has been established from both DSC
Some fluorine-containing nitrogen acids and their derivatives
Vij A, et al.
Coordination Chemistry Reviews, 158, 413-413 (1997)
Amino alcohol-derived chiral ionic liquids: structural investigations toward chiral recognition
Vasiloiu M, et al.
Tetrahedron Asymmetry, 26(18-19), 1069-1082 (2015)
Poly (ethylene oxide carbonates) solid polymer electrolytes for lithium batteries
Meabe L, et al.
Electrochimica Acta, 264, 367-375 (2018)

文章

Experts discuss challenges and production processes of nickel-rich layered oxide cathode materials in energy storage systems.

Lithium-ion batteries offer high energy density and cyclic performance for portable electronic devices.

The critical technical challenges associated with the commercialization of electric vehicle batteries include cost, performance, abuse tolerance, and lifespan.

Due to the adverse impact of the continued use of fossil fuels on the earth’s environment and climate, researchers have been asked to develop new approaches for producing power using renewable sources like wind and solar energy

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相關內容

The critical technical challenges associated with the commercialization of electric vehicle batteries include cost, performance, abuse tolerance, and lifespan.

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. What is the purity?

    1 answer
    1. Product 449504 is not tested for purity. The product undergoes IR testing as well as carbon, hydrogen, and fluorine NMR to confirm its identity but minor impurities may be present.

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