跳轉至內容
Merck
全部照片(1)

重要文件

79408

Sigma-Aldrich

磷腈配体 P1-叔丁基

≥97.0% (GC)

同義詞:

N′-叔丁基-N,N,N′,N′,N″,N″-六甲基亚氨代磷酸三酰胺, 叔丁基亚氨基-三(二甲氨基)正膦

登入查看組織和合約定價


About This Item

經驗公式(希爾表示法):
C10H27N4P
CAS號碼:
分子量::
234.32
Beilstein:
4178783
MDL號碼:
分類程式碼代碼:
12352001
PubChem物質ID:
NACRES:
NA.22
暫時無法取得訂價和供貨情況

化驗

≥97.0% (GC)

形狀

liquid

bp

347 °F/1013 hPa

官能基

amine

SMILES 字串

CN(C)P(N(C)C)(N(C)C)=NC(C)(C)C
CN(C)P(N(C)C)(N(C)C)=NC(C)(C)C

InChI

1S/C10H27N4P/c1-10(2,3)11-15(12(4)5,13(6)7)14(8)9/h1-9H3
1S/C10H27N4P/c1-10(2,3)11-15(12(4)5,13(6)7)14(8)9/h1-9H3

InChI 密鑰

YRNOSHBJMBLOSL-UHFFFAOYSA-N

其他說明

Sterically hindered, neutral nitrogen base with similar basicity as BEMP (Cat. No. 20025)citation; Base for dehydrating carbamate anions to isocyanates with POCl3 or P4O10citation
与BEMP具有相似碱性的空间位阻中性氮碱(货号20025)[1];用POCl3或P4O10将氨基甲酸根阴离子脱水成异氰酸酯的碱[2]

象形圖

Health hazardCorrosion

訊號詞

Danger

危險聲明

危險分類

Carc. 1B - Eye Dam. 1 - Muta. 1B - Skin Corr. 1B

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

235.4 °F - closed cup

閃點(°C)

113 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


從最近期的版本中選擇一個:

分析證明 (COA)

Lot/Batch Number

未看到正確版本?

如果您需要一個特定的版本,您可以透過批號來尋找特定憑證。

已經擁有該產品?

您可以在文件庫中找到最近購買的產品相關文件。

存取文件庫

T.E. Waldman et al.
Journal of the Chemical Society. Chemical Communications, 957-957 (1994)
R. Schwesinger et al
Angewandte Chemie (International Edition in English), 105, 1420-1420 (1994)
Lan-Fang Hu et al.
Molecules (Basel, Switzerland), 25(2) (2020-01-16)
The copolymerization of biorenewable succinic anhydride (SA) with propylene oxide (PO) is a promising way to synthesize biodegradable aliphatic polyesters. However, the catalytic systems for this reaction still deserve to be explored because the catalytic activity of the reported catalysts

文章

Phosphazene base reagents are available as monomeric (P1 and BEMP), dimeric (P2), and tetrameric (P4) bases with different side chains to control their sterical hindrance.

磷雜蔥基試劑有單體 (P1 和 BEMP)、二聚体 (P2) 和四聚體 (P4) 幾種,有不同的側鏈可控制其靜態障礙。

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

Reviews

No rating value

Active Filters

我們的科學家團隊在所有研究領域都有豐富的經驗,包括生命科學、材料科學、化學合成、色譜、分析等.

聯絡技術服務