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Merck
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761885

Sigma-Aldrich

1-(溴甲基)芘

同義詞:

1-芘甲基溴

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About This Item

經驗公式(希爾表示法):
C17H11Br
CAS號碼:
分子量::
295.17
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

形狀

solid

mp

140-145 °C

SMILES 字串

BrCc1ccc2ccc3cccc4ccc1c2c34

InChI

1S/C17H11Br/c18-10-14-7-6-13-5-4-11-2-1-3-12-8-9-15(14)17(13)16(11)12/h1-9H,10H2

InChI 密鑰

UGMXRPVWWWDPFC-UHFFFAOYSA-N

應用

1-(溴甲基)芘广泛用于合成荧光基团,用于多种分析物的荧光传感,包括生理pH下的金属离子(如cd2+、zn2+和三磷酸腺苷(ATP))传感。它也用于合成光引发剂(PI),用于丙烯酸酯的自由基聚合以及环氧-硅树脂和羟基醚的阳离子聚合。

象形圖

CorrosionExclamation mark

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


分析證明 (COA)

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The Journal of Organic Chemistry, 73(21), 8212-8218 (2008)
A tong-like fluorescence sensor for metal ions: perfect conformational switch of hinge sugar by pyrene stacking.
Yuasa H, et al.
Organic & Biomolecular Chemistry, 2(24), 3548-3556 (2004)
New insights into radical and cationic polymerizations upon visible light exposure: role of novel photoinitiator systems based on the pyrene chromophore.
Tehfe M A, et al.
Polym. Chem., 4(5), 1625-1634 (2013)
Unique sandwich stacking of pyrene-adenine-pyrene for selective and ratiometric fluorescent sensing of ATP at physiological pH.
Xu Z, et al.
Journal of the American Chemical Society, 131(42), 15528-15533 (2009)
Jing Wang et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 228, 117725-117725 (2019-11-14)
We developed PIM, a pyrene-based fluorescence sensor bearing an imidazole moiety and a carbonyl group as the binding sites for Fe3+ ions. The pyrene-based control compounds 1 and 2 were synthesized to demonstrate the structure-activity relationships. Compound 1, which contained

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