761435

[(二(1-金刚烷基)丁基膦基)-2-(2′-氨基-1,1′-联苯基)]钯(II)甲磺酸酯

95%

• 同義詞: [(二(1-金刚烷基)丁基膦基)-2-(2′-氨基-1,1′-联苯基)]钯(II) 甲磺酸酯, cataCXium-A-Pd-G3, 甲磺酸[(二(1-金刚烷基)丁基膦基)-2-(2′-氨基-1,1′-联苯基)]钯(II)
• 經驗公式（希爾表示法）: C₃₇H₅₂NO₃PPdS
• CAS號碼: 1651823-59-4
• 分子量：: 728.27
• 分類程式碼代碼: 12352300
• PubChem物質ID: 329766937
• NACRES: NA.22
• 形狀: solid
• 化驗: 95%

屬性

• 品質等級: 100
• 化驗: 95%
• 形狀: solid
• 特點: generation 3
• 反應適用性: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; reaction type: Cross Couplings
• 環保替代產品評分: old score: 16; new score: 2; Find out more about DOZN™ Scoring
• 環保替代產品特色: Waste Prevention; Atom Economy; Safer Solvents and Auxiliaries; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• 雜質: ≤3% acetone
• mp: 196-241 °C (decomposition)
• 官能基: phosphine
• 環保替代類別: Re-engineered
• SMILES 字串: CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CCCCP([C@@]34C[C@@H]5C[C@@H](C[C@@H](C5)C3)C4)[C@@]67C[C@@H]8C[C@@H](C[C@@H](C8)C6)C7
• InChI: 1S/C24H39P.C12H10N.CH4O3S.Pd/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h17-22H,2-16H2,1H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1/t17-,18+,19-,20-,21+,22-,23-,24-;;;
• InChI 密鑰: REYVZCOGMIXVNX-DVBMAMJVSA-M

描述

一般說明

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product belongs to category of Re-engineered products, showing key improvements in Green Chemistry Principles “Waste Prevention”, “Safer Solvents and Auxiliaries” and “Atom Economy”. Click here to view its DOZN scorecard.

應用

cataCXium^® A Pd G3 是一种第三代Buchwald预催化剂，可用于：

• 吡啶羧酸的直接邻位芳基化。[1][2]
• 催化Suzuki–Miyaura交叉偶联反应，以合成1-杂芳基-3-氮杂双环[3.1.0]己烷。[3]
• 炔烃的钯催化羰基碳全氟烷基化。[4]
• 各种 gem二取代环丙烷的合成过程中成对二(溴基)环丙烷的Suzuki–Miyaura 偶联反应。[5]
• 末端炔烃的溴全氟烷基化。[6]
• 芳香卤化物和炔烃的无铜Sonogashira 偶联反应，以形成 C-C键。[7]
• 有机三氟硼酸盐和芳基卤化物的Suzuki 交叉偶联反应。[8]

对于小规模和高通量用途，产品为ChemBeads ChemBeads (928305)

法律資訊

cataCXium is a registered trademark of Umicore AG & Co. KG

安全資訊

• 儲存類別代碼: 13 - Non Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable