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![双吡嗪并[2,3-f:2′,3′-h]喹喔啉-2,3,6,7,10,11-己腈 95% (HPLC)](/deepweb/assets/sigmaaldrich/product/structures/151/558/c0e2c95f-5228-4864-a7a5-4b9765a19840/640/c0e2c95f-5228-4864-a7a5-4b9765a19840.png)
品質等級
化驗
99% (HPLC)
形狀
solid
mp
310-315 °C
SMILES 字串
c1cnc2c(c1)c3nccnc3c4cccnc24
InChI
1S/C14H8N4/c1-3-9-11(15-5-1)12-10(4-2-6-16-12)14-13(9)17-7-8-18-14/h1-8H
InChI 密鑰
IBOSPAWVGHGUAV-UHFFFAOYSA-N
一般說明
Pyrazino[2,3-f][1,10]phenanthroline is a ligand which is used in the synthesis of copper(I)- phenanthroline complexes which are used in molecular device technology and in solar-energy conversion. It functions as an electron acceptor and the electron density is delocalized on the quinoxaline ring. The absorption and emission properties and the excited state lifetimes of these phenanthroline based copper complexes can be fine-tuned easily.[1]
應用
特點和優勢
Imparts improved directionality of electron transfer in excited copper complexes.[1]
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分析證明 (COA)
Lot/Batch Number
客戶也查看了
Synthesis, spectroscopic and electrochemical characterization of copper (I) complexes with functionalized pyrazino [2, 3-f]-1, 10-phenanthroline.
Barrientos, L., Araneda, C., Loeb, B., & Crivelli, I. G.
Polyhedron, 27(4), 1287-1295 (2008)
Yujie Sun et al.
Inorganic chemistry, 47(14), 6427-6434 (2008-06-25)
A series of ruthenium(II) complexes possessing ligands with an extended pi system were synthesized and characterized. The complexes are derived from [Ru(bpy)3](2+) (1, bpy = 2,2'-bipyridine) and include [Ru(bpy)2(tpphz)](2+) (2, tpphz = tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]phenazine), [Ru(bpy)2(dppx)](2+) (3, dppx = 7,8-dimethyldipyrido[3,2-a:2',3'-c]phenazine), [Ru(bpy)2(dppm2)](2+) (4
Ge; Hu; Wei;et al.
Journal of Luminescence, 131, 238-243 (2011)
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