746339

二氯三苯基膦[双（2-（乙硫基）乙基）胺]钌（II）

97%

• 同義詞: Ru-SNS catalyst
• 經驗公式（希爾表示法）: C₂₆H₃₄Cl₂NPRuS₂
• CAS號碼: 1462397-86-9
• 分子量：: 627.63
• MDL號碼: MFCD26960799
• 分類程式碼代碼: 12161600
• PubChem物質ID: 329765759
• NACRES: NA.22

屬性

• 化驗: 97%
• 形狀: solid
• 反應適用性: core: ruthenium; reagent type: catalyst
• 環保替代產品特色: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 300-310 °C
• 環保替代類別: Aligned,
• SMILES 字串: CCSCCN([H])CCSCC.Cl[Ru]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
• InChI: 1S/C18H15P.C8H19NS2.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-10-7-5-9-6-8-11-4-2;;;/h1-15H;9H,3-8H2,1-2H3;2*1H;/q;;;;+2/p-2
• InChI 密鑰: ZQGMNGJIEYHKBR-UHFFFAOYSA-L

描述

一般說明

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

應用

Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents.

Replacing Phosphorus with Sulfur for the Efficient Hydrogenation of Esters

Catalyst for the hydrogenation of esters to alcohols.

其他說明

"The mer-SNS complexes form isomers in solution. This is due to the different arrangements of the SEt groups relative to the SNS ligand plane. Two of the isomers have eclipsed SEt groups (arranged on one side of the SNS plane), and the third isomer has staggered SEt groups (occupying the opposite sides of the SNS plane)."

法律資訊

This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.

安全資訊

• 象形圖: GHS06
• 訊號詞: Danger
• 危險聲明: H302 + H312,H331
• 防範說明: P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P311
• 危險分類: Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral
• 儲存類別代碼: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable