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About This Item
經驗公式（希爾表示法）:
13CC14H11ClO
CAS號碼:
分子量：:
243.69
MDL號碼:
分類程式碼代碼:
12352005
PubChem物質ID:
NACRES:
NA.22
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同位素純度
≥97.0%
化驗
≥97.0% (GC)
形狀
solid
反應適用性
reaction type: C-C Bond Formation
官能基
acyl chloride
SMILES 字串
CC1(c2ccccc2-c3ccccc13)[13C](Cl)=O
InChI
1S/C15H11ClO/c1-15(14(16)17)12-8-4-2-6-10(12)11-7-3-5-9-13(11)15/h2-9H,1H3/i14+1
InChI 密鑰
ZQYOOHGEBHBNTP-UJKGMGNHSA-N
應用
COGen is a simple alternative for carbon monoxide generation in the application of palladium-catalyzed carbonylation reactions. This reagent has proved to be applicable in a wide range of applications and is compatible with several building blocks in the formation of ketones, amides, esters, etc.
For more information please visit: Technology Spotlight, Professor Skrystrup PPP
Use with the COware Platform
For more information please visit: Technology Spotlight, Professor Skrystrup PPP
Use with the COware Platform
包裝
Bottomless glass bottle. Contents are inside inserted fused cone.
聯結
Frequently Asked Questions are available for this Product.
訊號詞
Danger
危險聲明
危險分類
Eye Dam. 1 - Skin Corr. 1B
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
Philippe Hermange et al.
Journal of the American Chemical Society, 133(15), 6061-6071 (2011-03-31)
A new technique for the ex situ generation of carbon monoxide (CO) and its efficient incorporation in palladium catalyzed carbonylation reactions was achieved using a simple sealed two-chamber system. The ex situ generation of CO was derived by a palladium
Palladium-catalyzed carbonylative α-arylation for accessing 1,3-diketones.
Thomas M Gøgsig et al.
Angewandte Chemie (International ed. in English), 51(3), 798-801 (2011-12-06)
[14C]-Carbon Monoxide
Journal of Labelled Compounds & Radiopharmaceuticals, 55, 411-418 (2012)
Philippe Hermange et al.
Organic letters, 13(9), 2444-2447 (2011-04-08)
A carbonylative Heck reaction of aryl iodides and styrene derivatives employing a two-chamber system using a stable, crystalline, and nontransition metal based carbon monoxide source is reported. By applying near-stoichiometric amounts of the carbon monoxide precursor, an effective exploitation of
Mia N Burhardt et al.
The Journal of organic chemistry, 77(12), 5357-5363 (2012-05-23)
We have synthesized two isotopically labeled variants of the β-amyloid binding compound FSB possessing (13)C-labels on the two terminal aryl carboxylic acid moieties. One of these was also fully deuterated on the olefinic spacers. The (13)C-isotope labeling was achieved applying
文章
Studies in the field of carbonylation chemistry led to the discovery of a novel carbon monoxide (CO) delivery system.
What is COgen? What is COware? What is the SyTracks COgenerator system? And more questions answered.
相關內容
The Skrydstrup group has developed reagents and glassware for carrying out transition metal catalyzed carbonylations in a simple and safe manner.
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