701998

1,1′-双(二-环己基膦基)二茂铁二氯化钯

98%

• 同義詞: PdCl₂(dcypf)
• 經驗公式（希爾表示法）: C₃₄H₅₂Cl₂FeP₂Pd
• CAS號碼: 917511-90-1
• 分子量：: 755.90
• MDL號碼: MFCD11656081
• 分類程式碼代碼: 12161600
• PubChem物質ID: 329762337
• NACRES: NA.22

屬性

• 化驗: 98%
• 形狀: powder
• 反應適用性: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• mp: 294-300 °C
• 儲存溫度: −20°C
• SMILES 字串: [Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(C2CCCCC2)C3CCCCC3.[CH]4[CH][CH][C]([CH]4)P(C5CCCCC5)C6CCCCC6
• InChI: 1S/2C17H26P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*7-8,13-16H,1-6,9-12H2;2*1H;;/q;;;;;+2/p-2
• InChI 密鑰: HRAMBTUEZQOQRK-UHFFFAOYSA-L

描述

應用

1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II) or (Pd(dcpf)Cl₂) can be used as a catalyst in the synthesis of:

• α, β-unsaturated amides by hydroaminocarbonylation of alkynes with tertiary amines.[1]
• Quinazoline derivatives via Suzuki-Miyaura coupling reaction between of quinazolines containing unprotected NH₂ group and arylboronic acids.[2]
• α-aryl carbonyl compounds by α-arylation of ketones with aryl chlorides and aryl bromides.[3]

安全資訊

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: Eyeshields, Gloves, type N95 (US)