![9-氮杂双环[3.3.1]壬烷N-氧基 95%](/deepweb/assets/sigmaaldrich/product/structures/287/155/e2f4a2e1-1d4e-4bed-9187-9e16d23cbbbf/640/e2f4a2e1-1d4e-4bed-9187-9e16d23cbbbf.png)
AZADO (2-azaadamantane N-oxyl) can convert alcohols to their corresopnding carbonyl compounds more effectively than the traditional TEMPO reagent in sterically hindered environments.
全部照片(3)
About This Item
經驗公式（希爾表示法）:
C9H14NO
CAS號碼:
分子量：:
152.21
MDL號碼:
分類程式碼代碼:
12352000
PubChem物質ID:
NACRES:
NA.22
暫時無法取得訂價和供貨情況
推薦產品
化驗
90%
形狀
powder
反應適用性
reagent type: oxidant
mp
182-189 °C (D)
儲存溫度
2-8°C
SMILES 字串
[O]N1[C@@H]2C[C@H]3C[C@@H](C2)C[C@@H]1C3
InChI
1S/C9H14NO/c11-10-8-2-6-1-7(4-8)5-9(10)3-6/h6-9H,1-5H2/t6-,7+,8-,9+
InChI 密鑰
BCJCJALHNXSXKE-SPJNRGJMSA-N
客戶也查看了
Ming Zhang et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(10), 3937-3941 (2015-01-22)
An increased supply of scarce or inaccessible natural products is essential for the development of more sophisticated pharmaceutical agents and biological tools, and thus the development of atom-economical, step-economical and scalable processes to access these natural products is in high
Masatoshi Shibuya et al.
Journal of the American Chemical Society, 128(26), 8412-8413 (2006-06-29)
Development of a stable nitroxyl radical class of catalysts, 2-azaadamantane N-oxyl (AZADO) and 1-Me-AZADO, for highly efficient oxidation of alcohols is described. AZADO and 1-Me-AZADO exhibit superior catalytic proficiency to TEMPO, converting various sterically hindered alcohols to the corresponding carbonyl
Takefumi Kuranaga et al.
Journal of the American Chemical Society, 135(14), 5467-5474 (2013-03-19)
Here we report the first total synthesis and the complete stereochemical assignment of yaku'amide A. Yaku'amide A (1) was isolated from a sponge Ceratopsion sp. as an extremely potent cytotoxin. Its structure was determined except for the C4-stereochemistry in the
Takuya Isogai et al.
Biomacromolecules, 11(6), 1593-1599 (2010-05-18)
Curdlan, amylodextrin, and regenerated cellulose fiber were subjected to electromediated oxidation with a 4-acetamido-TEMPO catalyst in a buffer at pH 6.8 without NaClO or NaClO(2). More than 90% of the C6 primary hydroxyls of Curdlan and amylodextrin were converted to
文章
TEMPO（2,2,6,6-四甲基哌啶氧基或2,2,6,6-四甲基哌啶1-氧基）及其衍生物在有机氧化反应催化剂中可以作为稳定的硝酰基使用。TEMPO由Lebedev和Kazarnovskii于1960年发现，其具有的稳定自由基性质得益于其庞大的取代基团阻碍了自由基与其他分子之间发生反应。
-
What are the benefits of the organocatalyst 2-Azaadamantane-N-oxyl, Product 701718?
1 answer-
Helpful?
-
-
What is the Department of Transportation shipping information for this product?
1 answer-
Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
Helpful?
-
Active Filters
我們的科學家團隊在所有研究領域都有豐富的經驗，包括生命科學、材料科學、化學合成、色譜、分析等.
聯絡技術服務
