695157

双(3,5-二甲苯基)磷

• 經驗公式（希爾表示法）: C₁₆H₁₉P
• CAS號碼: 71360-06-0
• 分子量：: 242.30
• MDL號碼: MFCD01074629
• 分類程式碼代碼: 12352103
• PubChem物質ID: 329761721
• NACRES: NA.22

屬性

• 形狀: liquid
• 反應適用性: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• 折射率: n20/D 1.599
• 密度: 1.017 g/mL at 25 °C
• 官能基: phosphine
• SMILES 字串: Cc1cc(C)cc(Pc2cc(C)cc(C)c2)c1
• InChI: 1S/C16H19P/c1-11-5-12(2)8-15(7-11)17-16-9-13(3)6-14(4)10-16/h5-10,17H,1-4H3
• InChI 密鑰: GPFIUEZTNRNFGD-UHFFFAOYSA-N

描述

應用

Bis(3,5-dimethylphenyl)phosphine can be used as a reactant to prepare:

• Iron(II) chiral diimine diphosphine complexes as catalysts for the asymmetric transfer hydrogenation of ketones.[1]
• The complex of iridium with biphenol phosphite-phosphine bidentate ligand as an asymmetric catalyst for the hydrogenation of N-arylimines.[2]
• Chiral phosphines with excellent stereoselectivity by 1, 4 addition reaction with α,β-unsaturated aldehydes using a palladium catalyst.[3]

法律資訊

Kanata Chemical Technologies, Inc. 产品

安全資訊

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H302
• 危險分類: Acute Tox. 4 Oral
• 儲存類別代碼: 10 - Combustible liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: >230.0 °F
• 閃點（°C）: > 110 °C
• 個人防護裝備: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter