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About This Item
經驗公式（希爾表示法）:
C21H34N2O2
CAS號碼:
分子量：:
346.51
MDL號碼:
分類程式碼代碼:
12352002
PubChem物質ID:
NACRES:
NA.22
推薦產品
化驗
96%
形狀
solid
光學活性
[α]22/D -170°, c = 1 in chloroform
mp
180-186 °C
儲存溫度
2-8°C
SMILES 字串
CC(C)[C@H](N(C)C=O)C(=O)Nc1cc(cc(c1)C(C)(C)C)C(C)(C)C
InChI
1S/C21H34N2O2/c1-14(2)18(23(9)13-24)19(25)22-17-11-15(20(3,4)5)10-16(12-17)21(6,7)8/h10-14,18H,1-9H3,(H,22,25)/t18-/m0/s1
InChI 密鑰
OVKNTNIBDGTNQY-SFHVURJKSA-N
應用
用于合成手性 1,2-二芳基取代氮杂环丙烷。
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
分析證明 (COA)
輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號，寫有 ‘Lot’或‘Batch’.。
Andrei V Malkov et al.
The Journal of organic chemistry, 72(4), 1315-1325 (2007-02-10)
Asymmetric reduction of ketimines 1 with trichlorosilane can be catalyzed by N-methylvaline-derived Lewis-basic formamides 3a-d with high enantioselectivity (< or =95% ee) and low catalyst loading (1-5 mol %) at room temperature in toluene. Appending a fluorous tag, as in
Enantioselective synthesis of 1,2-diarylaziridines by the organocatalytic reductive amination of alpha-chloroketones.
Andrei V Malkov et al.
Angewandte Chemie (International ed. in English), 46(20), 3722-3724 (2007-04-07)
Andrei V Malkov et al.
Organic letters, 6(13), 2253-2256 (2004-06-18)
[reaction: see text] Asymmetric reduction of ketimines 1 with trichlorosilane can be catalyzed by a new N-methyl L-valine derived Lewis basic organocatalyst, such as 4d, with high enantioselectivity. The structure-reactivity investigation suggests hydrogen bonding and arene-arene interactions between the catalyst
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