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Merck
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文件

672661

Sigma-Aldrich

2-(二叔丁基膦)-1-苯基-1H-吡咯

95%

同義詞:

cataCXium® PtB

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About This Item

經驗公式（希爾表示法）:
C18H26NP
CAS號碼:
672937-61-0
分子量：:
287.38
Beilstein:
9626114
MDL號碼:
MFCD05861612
分類程式碼代碼:
12352005
PubChem物質ID:
329760523
NACRES:
NA.22

化驗

95%

反應適用性

reaction type: Asymmetric synthesis
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Dehydrogenation
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

官能基

phosphine

SMILES 字串

CC(C)(C)P(c1cccn1-c2ccccc2)C(C)(C)C

InChI

1S/C18H26NP/c1-17(2,3)20(18(4,5)6)16-13-10-14-19(16)15-11-8-7-9-12-15/h7-14H,1-6H3

InChI 密鑰

DVVDGSKDQGMLPW-UHFFFAOYSA-N

相關類別

一般說明

与 Solvias AG 联合销售

法律資訊

WO 2004/101581
cataCXium is a registered trademark of Umicore AG & Co. KG

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)

分析證明 (COA)

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Hai T Dong et al.
Inorganic chemistry, 59(20), 14967-14982 (2020-09-30)
We previously reported the synthesis and preliminary characterization of a unique series of low-spin (ls) {FeNO}8-10 complexes supported by an ambiphilic trisphosphineborane ligand, [Fe(TPB)(NO)]+/0/-. Herein, we use advanced spectroscopic techniques and density functional theory (DFT) calculations to extract detailed information
Michelle Muñoz-Osses et al.
Dalton transactions (Cambridge, England : 2003), 47(39), 13861-13869 (2018-09-19)
Cyrhetrenyl aldehyde derivatives [(η5-C5H4CHO)Re(CO)2PR3] with R = methyl (Me, 2a), phenyl (Ph, 2b), and cyclohexyl (Cy, 2c) were synthesized by a photochemical reaction from the starting material [(η5-C5H4CHO)Re(CO)3] (1) and the corresponding phosphines. The complexes were fully characterized by FT-IR
Cen Tang et al.
ACS nano, 14(9), 11605-11612 (2020-09-01)
The capping reagent plays an essential role in the functional properties of gold nanoparticles (AuNPs). Multiple stimuli-responsive materials are generated via diverse surface modification. The ability of the organic ligand shell on a gold surface to create a porous shell
Xi Kang et al.
Chemical Society reviews, 49(17), 6443-6514 (2020-08-08)
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles, providing unique opportunities for investigating the quantum effects and precise structure-property correlations at the atomic level. As a versatile strategy, alloying can largely improve the physicochemical performances compared to
Xun Pan et al.
Dalton transactions (Cambridge, England : 2003), 49(42), 14941-14950 (2020-10-21)
The synthesis of four heteroleptic dinuclear Cu(i) complexes bearing tetraphosphine and diimine ligands was reported. Complexes 1-3 were successfully obtained through microwave synthesis while complex 4 was synthesized through traditionally stirring at room temperature. These complexes are listed as follows:
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cataCXium® Catalysts

cataCXium® ligands facilitate cross-coupling reactions, essential in polymer science, fine chemicals, and pharmaceutical industries.

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