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666025

Sigma-Aldrich

13,6-N-亚磺酰基乙酰氨基并五苯

97%

同義詞:

16-乙酰基-6,13-二氢-15-氧化物-13,6-(环硫亚氨基)并五苯, NSFAAP, 可溶性并五苯前体

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About This Item

經驗公式（希爾表示法）:
C24H17NO2S
CAS號碼:
454675-76-4
分子量：:
383.46
MDL號碼:
MFCD08457646
分類程式碼代碼:
12352103
PubChem物質ID:
24884196
NACRES:
NA.23
暫時無法取得訂價和供貨情況

化驗

97%

形狀

solid

mp

169-190 °C

溶解度

THF: soluble
dioxane: soluble
methylene chloride: soluble

螢光

λex 251 nm; λem 498 nm in chloroform

儲存溫度

−20°C

SMILES 字串

CC(=O)N1[C@@H]2c3cc4ccccc4cc3[C@@H](c5cc6ccccc6cc25)S1=O

InChI

1S/C24H17NO2S/c1-14(26)25-23-19-10-15-6-2-4-8-17(15)12-21(19)24(28(25)27)22-13-18-9-5-3-7-16(18)11-20(22)23/h2-13,23-24H,1H3/t23-,24+,28?

InChI 密鑰

HIABOOSIYBUBKB-XUEDKKMFSA-N

一般說明

13,6-N-Sulfinylacetamidopentacene (NSFAAP) is a highly soluble pentacene precursor that can be synthesized by Lewis acid-catalyzed Diels-Alder reaction of pentacene and N-sulfinylacetamide. It can be spin coated to form an organic thin film which can be used in organic electronics.[1]

應用

NSFAAP can be used as a conjugating polymer that can be used in designing of thin film transistors with field mobility of 0.27 cm2V-1s-1 and a threshold voltage parameter of -4.25 V.[1][2][3][4]

準備報告

干燥薄膜在 150-200°C 时可转化为并五苯

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Gloves

從最近期的版本中選擇一個：

分析證明 (COA)

Lot/Batch Number
MKBP8574V
MKBC1017V
MKBC1017
01929EJ
08924JH

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High-performance, solution-processed organic thin film transistors from a novel pentacene precursor
Afzali A, et al.
Journal of the American Chemical Society, 124(30), 8812-8813 (2002)
Ali Afzali et al.
Journal of the American Chemical Society, 124(30), 8812-8813 (2002-07-26)
The Lewis acid-catalyzed Diels-Alder reaction of the organic semiconductor pentacene with N-sulfinylacetamide yields a soluble adduct. Spin-coated thin films of this adduct undergo solid-phase conversion to form thin films of pentacene at moderate temperatures. Organic thin film transistors fabricated by
On-Demand Patterning of Nanostructured Pentacene Transistors by Scanning Thermal Lithography
Shaw JE
Advanced Materials, 25(4), 552-558 (2013)
An organic thin film transistor based non-volatile memory with zinc oxide nanoparticles
Lee WK, et al.
Thin Solid Films, 519(15), 5208-5211 (2011)
Enhanced thin-film transistor performance by combining 13, 6-N-sulfinylacetamidopentacene with printed PEDOT: PSS electrodes
Luzio A, et al.
Chemistry of Materials, 23(4), 1061-1069 (2011)
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文章

Silylethyne-substituted Pentacenes

Silylethyne substitution offers an opportunity to tune solubility for application-specific needs and self-assembly for electronic performance and has yielded semiconductors with excellent device performance.

Soluble Pentacene Precursors

Fabrication procedure of organic field effect transistor device using a soluble pentacene precursor.

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