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重要文件

579726

Sigma-Aldrich

Grubbs Catalyst® M102

Umicore, 97%

同義詞:

Grubbs Catalyst® M1a (C823), Grubbs Catalyst®第一代催化剂, 双(三环己基膦)亚苄基钌(IV)二氯化物, 苯基亚甲基双(三环己基磷)二氯化钌

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About This Item

經驗公式(希爾表示法):
C43H72Cl2P2Ru
CAS號碼:
分子量::
822.96
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22


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品質等級

化驗

97%

反應適用性

core: ruthenium
reagent type: catalyst
reaction type: Ring-Opening Polymerization

mp

153 °C (dec.)

儲存溫度

2-8°C

SMILES 字串

C[Ph].P(C1CCCCC1)(C2CCCCC2)C3CCCCC3.P(C4CCCCC4)(C5CCCCC5)C6CCCCC6.Cl.Cl.[Ru]

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應用

第一个被广泛用于有机合成的复分解催化剂。适用于各种反应条件下末端烯烃的无环二烯复分解聚合(ADMET)、应变环烯烃的开环复分解聚合(ROMP)、开环复分解(ROM)、烯烃交叉复分解(CM)和关环复分解(RCM)。

了解我们的复分解催化剂的更多信息。

法律資訊

Umicore 产品

有关更多信息,请访问http://www.pmc.umicore.com。
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

象形圖

Flame

訊號詞

Warning

危險聲明

危險分類

Flam. Sol. 2

儲存類別代碼

4.1B - Flammable solid hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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分析證明 (COA)

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Brummer, O.; Ruckert, a.; Blechert, S.
Chemistry (Weinheim An Der Bergstrasse, Germany), 3, 441-441 (1997)
Brzezinska, K.; Wolfe, P. S.
Macromolecular Chemistry and Physics, 197, 2065-2065 (1996)
Michaut, M.; Parrain, J.-L.; Santelli, M.
Chemical Communications (Cambridge, England), 2567-2567 (1998)
Charvet, R.: Novak, B. M.
Macromolecules, 34, 7680-7680 (2001)
Young-Woo Kim et al.
Nature protocols, 6(6), 761-771 (2011-06-04)
This protocol provides a detailed procedure for the preparation of stapled α-helical peptides, which have proven their potential as useful molecular probes and as next-generation therapeutics. Two crucial features of this protocol are (i) the construction of peptide substrates containing

文章

Trost group's protocol yields α-vinylsilanes from terminal acetylenes using [Cp*Ru(MeCN)3]PF6 catalyst and others for hydrosilylation.

Trost 小組的方案使用 [Cp*Ru(MeCN)3]PF6 催化劑和其他催化劑進行水解作用,從末端乙炔中得到 α-乙烯基硅烷。

相關內容

Research focuses on ruthenium alkylidene complexes for versatile olefin metatheses catalysis in the Grubbs group.

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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