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515884

Sigma-Aldrich

三氟甲磺酸铝

99.9% trace metals basis

同義詞:

三(三氟甲烷)铝, 三(三氟甲磺酸铝)铝, 三(三氟磺酸)铝

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About This Item

線性公式:
(CF3SO3)3Al
CAS號碼:
分子量::
474.19
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

化驗

99.9% trace metals basis

反應適用性

core: aluminum
reagent type: catalyst

mp

300 °C (lit.)

SMILES 字串

[Al+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F

InChI

1S/3CHF3O3S.Al/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3

InChI 密鑰

FKOASGGZYSYPBI-UHFFFAOYSA-K

應用

三氟甲磺酸铝 (三氟磺酸铝或Al(OTf)3) 可用作以下反应的催化剂:
  • 通过不饱和醇的环化异构化进行环醚的区域选择性合成。
  • 糖类转化为5-羟甲基糠醛 (5-HMF)。
  • 与Pd(OAc)2/BINAP 一起参与苯乙炔的甲氧羰基化反应。

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


分析證明 (COA)

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Recyclable Pd (OAc) 2/Ligand/Al (OTf) 3 Catalyst for the Homogeneous Methoxycarbonylation and Hydrocarboxylation Reactions of Phenylacetylene
Williams DBG, et al.
Organometallics, 30(18), 4968-4973 (2011)
Aluminium (III) trifluoromethanesulfonate as an efficient catalyst for the intramolecular hydroalkoxylation of unactivated olefins: experimental and theoretical approaches
Coulombel L, et al.
Chemistry?A European Journal , 12(24), 6356-6365 (2006)
Valorization of an underused sugar derived from hemicellulose: Efficient synthesis of 5-hydroxymethylfurfural from mannose with aluminum salt catalyst in dimethyl sulfoxide/water mixed solvent
Jia S, et al.
Royal Society of Chemistry Advances, 7(62), 39221-39227 (2017)
Shaochen Zhang et al.
Science (New York, N.Y.), 364(6435), 45-51 (2019-04-06)
Accessing enantiomerically enriched amines often demands oxidation-state adjustments, protection and deprotection processes, and purification procedures that increase cost and waste, limiting applicability. When diastereomers can be formed, one isomer is attainable. Here, we show that nitriles, largely viewed as insufficiently
Yasuyuki Muto et al.
Bioscience, biotechnology, and biochemistry, 76(11), 2162-2164 (2012-11-08)
Biotin is one of the most useful tags in (bio)analytical science due to its specific interaction with avidin, but is not easy to convert because of its low solubility in most solvents. Friedel-Crafts acylation of biotin acid chloride in triflic

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