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Sigma-Aldrich

4-甲氧基苯基溴化镁 溶液

0.5 M in THF

同義詞:

(4-Methoxyphenyl)magnesium bromide, 4-Anisylmagnesium bromide, p-Methoxyphenylmagnesium bromide, Bromo(4-methoxyphenyl)magnesium

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About This Item

線性公式:
CH3OC6H4MgBr
CAS號碼:
13139-86-1
分子量：:
211.34
MDL號碼:
MFCD00013515
分類程式碼代碼:
12352103
PubChem物質ID:
24870649
NACRES:
NA.22
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反應適用性

reaction type: Grignard Reaction

濃度

0.5 M in THF

bp

65-67 °C

密度

0.955 g/mL at 25 °C

SMILES 字串

COc1ccc([Mg]Br)cc1

InChI

1S/C7H7O.BrH.Mg/c1-8-7-5-3-2-4-6-7;;/h3-6H,1H3;1H;/q;;+1/p-1

InChI 密鑰

JKXAZEXIOPFJSC-UHFFFAOYSA-M

相關類別

應用

4-甲氧基苯基溴化镁是一种通用的格氏试剂，可用于：
  • 卟啉去炔化和用镁取代金属中心。[1]
  • 合成微管蛋白聚合抑制剂 2-氨基-3,4,5-三甲氧基二苯甲酮。[2]
  • （−）-centrolobine 的全合成。[3]

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

標靶器官

Central nervous system, Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

-4.0 °F

閃點（°C）

-20 °C

從最近期的版本中選擇一個：

分析證明 (COA)

Lot/Batch Number
SHBQ3473
SHBN0351
SHBM5297
SHBM2074
SHBK1564

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Two successive one-pot reactions leading to the expeditious synthesis of (−)-centrolobine.
Boulard L, et al.
Tetrahedron Letters, 45(35), 6603-6605 (2004)
Demetalation of Metal Porphyrins via Magnesium Porphyrins by Reaction with Grignard Reagents.
Murakami K, et al.
Chemistry?A European Journal , 19(28), 9123-9126 (2013)
2?Amino?3, 4, 5?Trimethoxybenzophenones as Potent Tubulin Polymerization Inhibitors.
Chuang H Y, et al.
ChemMedChem, 6(3), 450-456 (2011)
Ryosuke Koyama et al.
Bioorganic & medicinal chemistry, 28(11), 115492-115492 (2020-04-16)
Effective chemotherapy for solid cancers is challenging due to a limitation in permeation that prevents anticancer drugs from reaching the center of the tumor, therefore unable to limit cancer cell growth. To circumvent this issue, we planned to apply the

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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