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Sigma-Aldrich

氯化钌 (III) 水合物

99.98% trace metals basis

同義詞:

三氯化钌

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About This Item

線性公式:
RuCl3 · xH2O
CAS號碼:
14898-67-0
分子量：:
207.43 (anhydrous basis)
EC號碼:
233-167-5
MDL號碼:
MFCD00149844
分類程式碼代碼:
12352302
PubChem物質ID:
24870096
NACRES:
NA.23
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品質等級

100

化驗

99.98% trace metals basis

形狀

powder and chunks

反應適用性

reagent type: catalyst
core: ruthenium

雜質

≤250.0 ppm Trace Metal Analysis

SMILES 字串

O.Cl[Ru](Cl)Cl

InChI

1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3

InChI 密鑰

BIXNGBXQRRXPLM-UHFFFAOYSA-K

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相關類別

一般說明

氯化钌（III）水合物具有优异的催化活性，这是因为钌的氧化还原性质适用于燃料电池和其它电化学设备。 它能够促进电荷转移并具有光敏行为。

應用

氯化钌（III）水合物可用于：
  • 作为制备超低钌负载石墨烯气凝胶的前体，该气凝胶在析氢反应（HER）、析氧反应（OER）和氧还原反应（ORR）中表现出电催化性能。
  • 作为掺杂剂，通过旋涂技术制备用于介观钙钛矿太阳能电池的掺钌TiO22 电子传输层。这有助于提高光转换效率和空气稳定性。
  • 通过小分子自组装热解法制备超均匀钌纳米簇催化剂。这些催化剂在所有pH条件下在锌空气电池中表现出优异的析氢活性。

其他說明

可溶型

訊號詞

Danger

危險聲明

H302,H314,H411

危險分類

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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分析證明 (COA)

Lot/Batch Number
0000425005
0000425005
0000419184
0000419183
0000419184

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Fujita, S.-I., et al.
J. Catal., 255, 95-95 (2004)
Cho, C.S. et al.
Tetrahedron Letters, 40, 1499-1499 (1999)
Won-Hee Kim et al.
Organic letters, 8(12), 2543-2545 (2006-06-02)
An efficient oxidant-free oxidation for a wide range of alcohols was achieved by a recyclable ruthenium catalyst. The catalyst was prepared from readily available reagents by a one-pot synthesis through nanoparticle generation and gelation. [structure: see text]
Yao Zhang et al.
European journal of medicinal chemistry, 86, 449-455 (2014-09-10)
Ruthenium-based anticancer complexes have become increasingly popular for study over the last two decades. Although ruthenium complexes are currently being investigated in clinical trials, there are still some difficulties with their delivery and associated side effects. Human serum albumin (HSA)-based
Huaiyi Huang et al.
Dalton transactions (Cambridge, England : 2003), 44(35), 15602-15610 (2015-08-08)
Ruthenium complexes have been considered as promising substitutes for cisplatin in cancer chemotherapy. However, novel ruthenium-based therapies are faced with some limitations, such as unimpressive cytotoxicity toward solid tumors. Herein, we designed and synthesized phenyl-substituted terpyridyl ruthenium(ii) complexes ([Ru(tpy)(bpy)Cl](+) (Ru1)
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