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418560

Sigma-Aldrich

甲基化聚(三聚氰胺-co-甲醛), 溶液

average Mn ~432, 84 wt. % in 1-butanol

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About This Item

線性公式:
(C4H8N6O)n
CAS號碼:
MDL號碼:
分類程式碼代碼:
12162002
NACRES:
NA.23
暫時無法取得訂價和供貨情況

形狀

liquid

品質等級

分子量

average Mn ~432

濃度

84 wt. % in 1-butanol

折射率

n20/D 1.515

bp

118 °C

密度

1.157 g/mL at 25 °C

SMILES 字串

Nc1nc(nc(n1)N)N.O=C

InChI

1S/C3H6N6.CH2O/c4-1-7-2(5)9-3(6)8-1;1-2/h(H6,4,5,6,7,8,9);1H2

InChI 密鑰

IVJISJACKSSFGE-UHFFFAOYSA-N

一般說明

聚(三聚氰胺-co-甲醛)甲基化溶液(PMF)是热引发的交联剂,其形成光学透明的溶液。 它可以通过与还原共混物中的羟基单元的酚基团连接而与聚(4-乙烯基苯酚)(PVP)连接。[1][2]

應用

PMF可用于制备PVP基油墨,其可用于喷墨印刷,用于开发电子元件,例如:
  • 有机薄膜晶体管[3]
  • 射频电容器[4]
  • 平行板电容器[5]
  • 金属绝缘金属(MIM)电容器[6]

訊號詞

Danger

危險分類

Acute Tox. 4 Inhalation - Carc. 2 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

Lot/Batch Number

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Inkjet-printed thin film radio-frequency capacitors based on sol-gel derived alumina dielectric ink.
McKerricher G, et al.
Ceramics International, 43(13), 9846-9853 (2017)
Inkjet Printed Parallel Plate Capacitors Using PVP Polymer Dielectric Ink on Flexible Polyimide Substrates.
IEEE Engineering in Medicine and Biology Society (EMBC), 4277-4280 (2018)
Poly (melamine-co-formaldehyde) methylated effect on the interface states of metal/polymer/p-Si Schottky barrier diode.
Tozlu C and Mutlu A
Synthetic Metals, 211, 99-106 (2016)
Effects of processing variable on melamine-formaldehyde aerogel formation.
Nguyen MH and Dao L
Journal of Non-Crystalline Solids, 225, 51-57 (1998)
Scaling of contact metal induced hysteresis in solution processed organic thin film transistors.
Karunakaran L, et al
Organic Electronics, 65, 15-18 (2019)

相關內容

One of the best known and highest performing smallmolecule organic semiconductors is TIPS-Pentacene. TIPS-Pentacene is soluble in a wide range of solvents and does not require a thermal conversion after deposition.

Questions

1–4 of 4 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. What wt% of formaldehyde is present in the methylated poly(melamine-co-formaldehyde) solution?

    1 answer
    1. The amount of free formaldehyde in this solution is typically less than 1 percent. The exact ratio of melamine to formaldehyde in the polymer is not determined, therefore the weight percent of formaldehyde in the polymer is not known.

      Helpful?

  4. What's the curing temperature of this product? What is the suitable solvent? Is it soluble i water as well as organic oil?

    1 answer
    1. This is an 84 wt.% solution in 1-butanol. The solubility and curing temperature of this product is not determined. The link below is to a review article which may be helpful:
      https://www.nature.com/articles/pj2012162

      Helpful?

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