推薦產品
化驗
97%
形狀
liquid
折射率
n20/D 1.463 (lit.)
bp
130-131 °C/14 mmHg (lit.)
密度
1.362 g/mL at 25 °C (lit.)
儲存溫度
2-8°C
SMILES 字串
CCOP(=O)(OCC)C(Cl)(Cl)Cl
InChI
1S/C5H10Cl3O3P/c1-3-10-12(9,11-4-2)5(6,7)8/h3-4H2,1-2H3
InChI 密鑰
RVAQSYWDOSHWGP-UHFFFAOYSA-N
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一般說明
Addition reaction of diethyl (trichloromethyl)phosphonate to olefins by non-chain catalytic reactions catalyzed by copper amine complexes has been reported.[1] Irradiation of diethyl (trichloromethyl)phosphonate in MeCN is reported to afford corresponding monoesters and olefins, via photochemical type II elimination reaction.[2]
應用
Diethyl (trichloromethyl)phosphonate may be used in the synthesis of chlorovinyl phosphonates via reaction with aldehydes and ketones.[3]
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
10 - Combustible liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
235.4 °F - closed cup
閃點(°C)
113 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Addition of diethyl trichloromethylphosphonate to olefins catalysed by copper complexes.
Tetrahedron Letters, 35(21), 3537-3538 (1994)
A novel synthesis of phosphonates from diethyl (trichloromethyl) phosphonate.
The Journal of Organic Chemistry, 59(!6), 4548-4550 (1994)
Photochemical type I and II elimination reactions of dialkyl (trichloromethyl) phosphonates.
Bulletin of the Chemical Society of Japan, 53(5), 1421-1424 (1980)
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