推薦產品
化驗
98%
形狀
liquid
折射率
n20/D 1.425 (lit.)
bp
195-198 °C (lit.)
密度
1.294 g/mL at 25 °C (lit.)
SMILES 字串
COC(=O)C[N+]([O-])=O
InChI
1S/C3H5NO4/c1-8-3(5)2-4(6)7/h2H2,1H3
InChI 密鑰
ALBSWLMUHHZLLR-UHFFFAOYSA-N
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應用
Methyl nitroacetate may be used:
- in the preparation of aromatic and heteroaromatic linear (E)-α-nitro-arylpentenoates
- to generate phenyliodonium ylide, used in the highly enantioselective and diastereoselective Cu(I)-catalyzed cyclopropanation of alkenes
- in the preparation of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate, via reaction with 4-nitrobenzylideneaniline
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
10 - Combustible liquids
水污染物質分類（WGK）
WGK 2
閃點（°F）
221.0 °F - closed cup
閃點（°C）
105 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
分析證明 (COA)
輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號，寫有 ‘Lot’或‘Batch’.。
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Andrew J Young et al.
Journal of the American Chemical Society, 130(43), 14090-14091 (2008-10-04)
The first electrophilic Pd(II)-catalyzed allylic C H alkylation is reported, providing a novel method for formation of sp3-sp3 C C bonds directly from C H bonds. A wide range of aromatic and heteroaromatic linear (E)-alpha-nitro-arylpentenoates are obtained as single olefin
Experimental and theoretical studies of Diels-Alder reaction between methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate and cyclopentadiene.
Jasinski R, et al.
Monatshefte fur Chemie / Chemical Monthly, 144(3), 327-335 (2013)
Benoît Moreau et al.
Journal of the American Chemical Society, 127(51), 18014-18015 (2005-12-22)
A highly enantioselective (up to 97.5% ee) and diastereoselective (95:5 dr trans/cis) Cu(I)-catalyzed cyclopropanation of alkenes using phenyliodonium ylide generated in situ from iodosobenzene and methyl nitroacetate is reported. The cyclopropanation took place with high enantioselectivity for a wide range
[Experimental establishment of the maximum permissible concentration of the methyl and ethyl esters of nitroacetic acid].
G I Sidorin et al.
Gigiena truda i professional'nye zabolevaniia, (7)(7), 49-51 (1980-07-01)
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