362174

(双环[2.2.1]庚-2,5-二烯)二氯钯(II)

98%

• 同義詞: Dichloro (norbornadiene)palladium(II), NSC 176915, PdCl₂(nbd)
• 經驗公式（希爾表示法）: C₇H₈Cl₂Pd
• CAS號碼: 12317-46-3
• 分子量：: 269.46
• EC號碼: 235-583-2
• MDL號碼: MFCD00134222
• 分類程式碼代碼: 12352300
• PubChem物質ID: 24862295
• NACRES: NA.22

屬性

• 化驗: 98%
• 反應適用性: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• mp: 260 °C (dec.) (lit.)
• SMILES 字串: Cl[Pd]Cl.[CH]1[CH]C2[CH][CH]C1C2
• InChI: 1S/C7H8.2ClH.Pd/c1-2-7-4-3-6(1)5-7;;;/h1-4,6-7H,5H2;2*1H;/q;;;+2/p-2
• InChI 密鑰: BNCRZJHZZCMDNP-UHFFFAOYSA-L

描述

應用

Catalyst for:

• Aerobic kinetic resolution of secondary alcohols
• Kinetic oxidative resolution of 1-phenyl ethanol
• Oxidative kinetic resolution-Claisen rearrangement sequence
• Aerobic oxidation of secondary alcohols

安全資訊

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves