346292

4,4-二甲基-2-苯基-2-噁唑啉

96%

• 經驗公式（希爾表示法）: C₁₁H₁₃NO
• CAS號碼: 19312-06-2
• 分子量：: 175.23
• MDL號碼: MFCD00030446
• 分類程式碼代碼: 12352100
• PubChem物質ID: 24861389
• NACRES: NA.22

屬性

• 化驗: 96%
• 折射率: n20/D 1.5322 (lit.)
• bp: 124 °C/20 mmHg (lit.)
• mp: 20-24 °C (lit.)
• 密度: 1.025 g/mL at 25 °C (lit.)
• SMILES 字串: CC1(C)COC(=N1)c2ccccc2
• InChI: 1S/C11H13NO/c1-11(2)8-13-10(12-11)9-6-4-3-5-7-9/h3-7H,8H2,1-2H3
• InChI 密鑰: UGNSMKDDFAUGFT-UHFFFAOYSA-N

描述

一般說明

4,4-Dimethyl-2-phenyl-2-oxazoline is an 2-aryl-2-oxazoline and has been tested as as ligand for the Suzuki coupling reaction of aryl bromides and arylboronic acids.[1] 4,4-Dimethyl-2-phenyl-2-oxazoline forms mildly hygroscopic complexes, of general formulae [ZnX₂(ox)₂] (ox =4,4-Dimethyl-2-phenyl-2-oxazoline), with ether solutions of [ZnX₂] (X = Cl, Br, I).Except ZnI₂, which does not form an isolable complex due to steric reasons.[2]

應用

4,4-Dimethyl-2-phenyl-2-oxazoline may be used in the synthesis of an ester-ammonium salt via rupture of oxazoline ring.[3]

安全資訊

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 10 - Combustible liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 217.4 °F - closed cup
• 閃點（°C）: 103 °C - closed cup
• 個人防護裝備: Eyeshields, Gloves, type ABEK (EN14387) respirator filter