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Merck
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332828

Sigma-Aldrich

2-丁酮肟

99%

同義詞:

甲乙酮肟

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About This Item

線性公式:
C2H5C(=NOH)CH3
CAS號碼:
分子量::
87.12
Beilstein:
1698241
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

3 (vs air)

品質等級

蒸汽壓力

<8 mmHg ( 20 °C)

化驗

99%

形狀

liquid

折射率

n20/D 1.442 (lit.)

bp

59-60 °C/15 mmHg (lit.)

溶解度

water: soluble 100 g/L at 25 °C

密度

0.924 g/mL at 25 °C (lit.)

SMILES 字串

CC\C(C)=N\O

InChI

1S/C4H9NO/c1-3-4(2)5-6/h6H,3H2,1-2H3/b5-4+

InChI 密鑰

WHIVNJATOVLWBW-SNAWJCMRSA-N

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一般說明

丁酮肟是一种抗氧化剂和封闭剂,用于合成水分散性封闭聚氨酯( blocked polyurethane)。

應用

以 2-丁酮肟为试剂和溶剂,合成了酮亚胺和 2,4-二吡啶-1,3,5-三氮杂戊二烯钯 (II) 配合物。它也用于合成新型的乙缩醛二亚胺钴配合物,[CoI2{((CH3CH2)(CH3)C=NO)2C(CH3)2}]。

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Carc. 1B - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 - STOT SE 1 - STOT SE 3

標靶器官

Blood, Central nervous system, Upper respiratory tract

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

143.5 °F - closed cup

閃點(°C)

61.97 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


分析證明 (COA)

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Paul E Newton et al.
Inhalation toxicology, 14(12), 1249-1260 (2002-11-28)
Methylethylketoxime, also known as MEKO or 2-butanone oxime (CAS No. 96-29-7), is a clear, colorless to light yellow liquid at room temperature. It is an industrial antioxidant used as an antiskinning agent in alkyd paint, an industrial blocking agent for
Michael J Derelanko et al.
Drug and chemical toxicology, 31(1), 97-114 (2007-12-29)
Acute and repeated oral and dermal rat toxicology studies of standard designs were conducted on four methyl ethyl ketoxime (MEKO) silanes and four methyl isobutyl ketoxime (MIBKO) silanes. Each compound contained either MEKO or MIBKO groups (but not both) and
Maximilian N Kopylovich et al.
Dalton transactions (Cambridge, England : 2003), (16)(16), 3074-3084 (2009-04-09)
[2 + 3] cycloaddition of the pyrrolin N-oxide (-)O[upper bond 1 start](+)N[double bond, length as m-dash]CHCH(2)CH(2)C[upper bond 1 end]Me(2) with 2-cyanopyridine NC(5)H(4)(2-CN) in the presence of PdCl(2) at room temperature in acetone gives the ketoimine palladium(II) complex cis-[PdCl(2){N(=[upper bond 1
Developmental toxicity studies of methyl ethyl ketoxime (MEKO) in rats and rabbits
Michael D J et al.
Drug and Chemical Toxicology, 26, 147-168 (2003)
P E Newton et al.
Inhalation toxicology, 13(12), 1093-1116 (2001-11-07)
To evaluate the oncogenic potential of methylethylketoxime (MEKO), CD-1 mice (50/sex/group) and F-344 rats (50/sex/group) were coexposed 6 h/day, 5 days/wk for 18 mo (mice) or 26 mo (rats) via whole-body inhalation exposures to target vapor concentrations of 0, 15

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