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Sigma-Aldrich

全氟（甲基环己烷）

technical grade, 90%

同義詞:

十一氟(三氟甲基)环己烷, 全氟甲基环己烷

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About This Item

線性公式:
C6F11CF3
CAS號碼:
355-02-2
分子量：:
350.05
Beilstein:
1915981
EC號碼:
206-573-5
MDL號碼:
MFCD00001468
分類程式碼代碼:
12352100
PubChem物質ID:
24858283
NACRES:
NA.22
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等級

technical grade

化驗

90%

形狀

liquid

折射率

n17/D 1.285 (lit.)

bp

76 °C (lit.)

密度

1.787 g/mL at 25 °C (lit.)

官能基

fluoro

SMILES 字串

FC(F)(F)C1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C1(F)F

InChI

1S/C7F14/c8-1(7(19,20)21)2(9,10)4(13,14)6(17,18)5(15,16)3(1,11)12

InChI 密鑰

QIROQPWSJUXOJC-UHFFFAOYSA-N

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相關類別

一般說明

氯仿和全氟（甲基环己烷）的混合物可用作“氟”双相反应的溶剂。[1]已有研究报道了全氟（甲基环己烷）的气相结构。[2]

應用

使用全氟（甲基环己烷）作为溶剂，研究一系列烃和碳氟化合物官能化的烟酸酯的亲氟性。[3]
全氟甲基环己烷可用作：
  • 反应物，用于通过与水中的四丁基碘化铵进行光化学反应合成全氟-2-甲基环己基-1-烯醇化物。[4]
  • 氟溶剂，用于以氟 Grubbs ′二代催化剂通过降冰片烯的开环复分解聚合 (ROMP) 合成聚降冰片烯。 [5]

它还可用作溶剂，研究一系列烃和碳氟化合物官能化烟酸酯的亲氟性。[3]

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Gloves

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分析證明 (COA)

Lot/Batch Number
BCCM2870
BCCK6779
BCCJ9387
BCCH4692
BCCG9941

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Vivian Ojogun et al.
Journal of fluorine chemistry, 131(7), 784-790 (2010-06-23)
The fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters (nicotinates) is measured from their partitioning behavior (log K(P)) in the biphasic solvent system of perfluoro(methylcyclohexane) (PFMC) and toluene. The chain length of the hydrocarbon or fluorocarbon alkyl
Development of Highly Active Ring Opening Metathesis Polymerization Catalyst Systems-A New Approach for Green Catalyst Design
Tuba R, et al.
Proceedings, 2011(1), EVO3-EVO3 (2011)
Stephanie S Adkins et al.
The journal of physical chemistry. B, 112(15), 4760-4769 (2008-03-28)
The technique of hydrophobic ion pairing was used to solubilize the lipase from Candida rugosa in a fluorinated solvent, perfluoromethylcyclohexane (PFMC), in complex with a perfluoropolyether (PFPE) surfactant, KDP 4606. The enzyme-surfactant complex was determined to have a hydrodynamic diameter
Graeme R Kafka et al.
The journal of physical chemistry. A, 114(41), 11022-11026 (2010-09-30)
When refining structures using gas electron diffraction (GED) data, assumptions are often made in order to reduce the number of required geometrical parameters. Where these relate to light, peripheral atoms there is little effect on the refined heavy-atom structure, which
Mei-Jy Jeng et al.
Critical care medicine, 34(4), 1099-1105 (2006-02-18)
To investigate the therapeutic effects of bronchoalveolar lavage (BAL) with either diluted surfactant (SBAL) or perfluorochemical liquid (PBAL), followed by either conventional mechanical ventilation (CMV) or partial liquid ventilation (PLV), on lung injury and proinflammatory cytokine production induced by meconium
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