26235

2-(3-氯丙基)-1,3-二噁戊环

≥97.0% (GC)

• 同義詞: 4-氯丁醛乙烯基乙缩醛
• 經驗公式（希爾表示法）: C₆H₁₁ClO₂
• CAS號碼: 16686-11-6
• 分子量：: 150.60
• Beilstein: 1236588
• MDL號碼: MFCD00043135
• 分類程式碼代碼: 12352100
• PubChem物質ID: 57648166
• NACRES: NA.22

屬性

• 品質等級: 100
• 化驗: ≥97.0% (GC)
• 形狀: liquid
• 折射率: n20/D 1.453
• bp: 93-94 °C/12 mmHg (lit.)
• 密度: 1.142 g/mL at 20 °C (lit.)
• 官能基: chloro; ether
• SMILES 字串: ClCCCC1OCCO1
• InChI: 1S/C6H11ClO2/c7-3-1-2-6-8-4-5-9-6/h6H,1-5H2
• InChI 密鑰: ZBPUNVFDQXYNDY-UHFFFAOYSA-N

描述

應用

2-(3-Chloropropyl)-1,3-dioxolane (2-(3′-chloropropyl)-1,3-dioxolane) is a masked γ-chlorobutyraldehyde and was used for the introduction of 3-(1,3-dioxolan-2-yl)propyl moiety[1][2][3]. It was also used in the synthesis of:

• (±)-histrionicotoxin and (±)-histrionicotoxin 235A using a two-directional strategy[4]
• 4-iodobutyraldehyde, 5-iodovaleraldehyde and 5-iodo-2-petanone[5]
• corresponding phosphonate[6]

其他說明

含掩蔽的 γ-氯丁醛，用于引入 3-(1,3-二氧戊环-2-基)丙基部分[1][2][3]；也可用于对应膦酸酯的制备和使用[6]

安全資訊

• 儲存類別代碼: 10 - Combustible liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 174.2 °F - closed cup
• 閃點（°C）: 79 °C - closed cup
• 個人防護裝備: Eyeshields, Gloves, type ABEK (EN14387) respirator filter