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Sigma-Aldrich

1,4,8,11-四氮杂环十四烷

98% (GC)

同義詞:

1,4,8,11-四氮环十四烷

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About This Item

經驗公式（希爾表示法）:
C10H24N4
CAS號碼:
295-37-4
分子量：:
200.32
Beilstein:
111811
EC號碼:
206-039-1
MDL號碼:
MFCD00005105
分類程式碼代碼:
12352005
PubChem物質ID:
24855689
NACRES:
NA.22
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化驗

98% (GC)

mp

184-186 °C (lit.)

SMILES 字串

C1CNCCNCCCNCCNC1

InChI

1S/C10H24N4/c1-3-11-7-9-13-5-2-6-14-10-8-12-4-1/h11-14H,1-10H2

InChI 密鑰

MDAXKAUIABOHTD-UHFFFAOYSA-N

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相關類別

一般說明

1,4,8,11-四氮杂环十四烷是一种氮杂大环，可形成比开链配体更稳定的金属配合物。[1]

應用

1,4,8,11-四氮杂环十四烷(cyclam)可作为配体用于合成：
  • 氰化物桥联FeIII-CuII配合物。[2]
  • 具有抗菌性的芬那酸锌配合物[Zn(cyclam)(fen)2]，fen=芬那酸。[3]
  • Zn(II)氟芬那酸
  • (flu)配合物，[Zn(cyclam)(flu)2]。[4]
  • 多金属氧酸盐-有机金属框架，如[{Cu(cyclam)}3(W7O24)].15.5.H2O。[5]

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319

危險分類

Eye Irrit. 2 - Skin Irrit. 2

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

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分析證明 (COA)

Lot/Batch Number
MKCX1975
MKCX0407
MKCX0406
MKCX0405
MKCR3837

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Michael Schmittel et al.
Chemical communications (Cambridge, England), 48(96), 11730-11732 (2012-10-20)
The two states of a new nanomechanical switch were quantitatively and reversibly populated in several subsequent switching cycles using either Cu(+) or cyclam as chemical inputs. State II was demonstrated to cis-trans isomerise diazastilbene upon irradiation selectively in the presence
Prasenjit Mahato et al.
Inorganic chemistry, 50(9), 4162-4170 (2011-04-01)
Two chromogenic complexes, L.Zn (where L is (E)-4-((4-(1,4,8,11-tetraazacyclotetradecan-1-ylsulfonyl)phenyl)diazenyl)-N,N-dimethylaniline) and its [2]pseudorotaxane form (α-CD.L.Zn), were found to bind preferentially to adenosine triphosphate (ATP), among all other common anions and biologically important phosphate (AMP, ADP, pyrophosphate, and phosphate) ions in aqueous HEPES
Thermally-Triggered Crystal Dynamics and Permanent Porosity in the First Heptatungstate-Metalorganic Three-Dimensional Hybrid Framework.
Martin-Caballero J, et al.
Chemistry?A European Journal , 23(59), 14962-14974 (2017)
Luis G Alves et al.
Dalton transactions (Cambridge, England : 2003), 41(47), 14288-14298 (2012-10-09)
Novel Bn(2)Cyclam-based zirconium complexes of the type (Bn(2)Cyclam)Zr(X)(X') (3, X = X' = OPh; 4, X = X' = SPh; 5, X = Cl, X' = O(i)Pr) were synthesized in good yields via metathesis routes involving the reaction of the
Novel Zn (II) complexes with non-steroidal anti-inflammatory ligand, flufenamic acid: Characterization, topoisomerase I inhibition activity, DNA and HSA binding studies.
Smolkova R, et al.
Journal of Inorganic Biochemistry, 177(17), 143-158 (2017)
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