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339652

Sigma-Aldrich

轮环藤宁

97%

同義詞:

1,4,7,10-四氮环十二烷

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About This Item

經驗公式(希爾表示法):
C8H20N4
CAS號碼:
分子量::
172.27
Beilstein:
606114
MDL號碼:
分類程式碼代碼:
12162002
PubChem物質ID:
NACRES:
NA.23

化驗

97%

形狀

solid

mp

110-113 °C (lit.)

SMILES 字串

C1CNCCNCCNCCN1

InChI

1S/C8H20N4/c1-2-10-5-6-12-8-7-11-4-3-9-1/h9-12H,1-8H2

InChI 密鑰

QBPPRVHXOZRESW-UHFFFAOYSA-N

一般說明

轮环藤宁是一种微环四胺(microcyclic tetramine),可用作与表面金属阳离子形成配位键的配体。它可用作合成前体。它可以通过二硫代草酰胺与过量溴乙烷的S-烷基化反应来制备。

應用

轮环藤宁是一种氮杂环(azamocrocycle),可用于开发检测金属离子的荧光纳米传感器。

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


分析證明 (COA)

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Choy Theng Loh et al.
Bioconjugate chemistry, 24(2), 260-268 (2013-01-09)
Pseudocontact shifts (PCS) from paramagnetic lanthanide ions present powerful long-range structural restraints for structural biology by NMR spectroscopy, but site-specific tagging of proteins with lanthanides remains a challenge, as most of the available lanthanide tags require proteins with single cysteine
Novel" multipoint" molecular recognition of nucleobases by a new zinc (II) complex of acridine-pendant cyclen (cyclen= 1, 4, 7, 10-tetraazacyclododecane)
Shionoya M, et al.
Journal of the American Chemical Society, 116(9), 3848-3859 (1994)
Azamacrocycle activated quantum dot for zinc ion detection
Ruedas-Rama MJ and Hall EAH
Analytical Chemistry, 80(21), 8260-8268 (2008)
Mohd Zulkefeli et al.
Inorganic chemistry, 50(20), 10113-10123 (2011-09-23)
In Nature, organized nanoscale structures such as proteins and enzymes are formed in aqueous media via intermolecular interactions between multicomponents. Supramolecular and self-assembling strategies provide versatile methods for the construction of artificial chemical architectures for controlling reaction rates and the
A new synthesis of cyclen (1, 4, 7, 10-tetraazacyclododecane)
Weisman GR and Reed DP
The Journal of Organic Chemistry, 61(15), 5186-5187 (1996)

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