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250724

Sigma-Aldrich

1,4,8,11-四硫杂环十四烷

95%

同義詞:

四硫环十四烷

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About This Item

經驗公式（希爾表示法）:
C10H20S4
CAS號碼:
24194-61-4
分子量：:
268.53
MDL號碼:
MFCD00010048
分類程式碼代碼:
12352100
PubChem物質ID:
24855070
NACRES:
NA.22

品質等級

100

化驗

95%

mp

118-121 °C (lit.)

SMILES 字串

C1CSCCSCCCSCCSC1

InChI

1S/C10H20S4/c1-3-11-7-9-13-5-2-6-14-10-8-12-4-1/h1-10H2

InChI 密鑰

WMVHWZHZRYGGOO-UHFFFAOYSA-N

一般說明

1,4,8,11-Tetrathiacyclotetradecane is a tetradentate thioether and forms complexes with ruthenium. It is also referred as thio-crown [14]aneS(4) or sulfur crown-ether analog.

應用

1,4,8,11-Tetrathiacyclotetradecane has been used in liquid-liquid extraction of metal ions.

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

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分析證明 (COA)

Lot/Batch Number
03722BW
13313HR
08502JR

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Siu-Chung Chan et al.
Inorganic chemistry, 50(22), 11636-11643 (2011-10-26)
Ruthenium complexes containing 2-(2-nitrosoaryl)pyridine (ON(^)N) and tetradentate thioether 1,4,8,11-tetrathiacyclotetradecane ([14]aneS4), [Ru(ON(^)N)([14]aneS4)](2+) [ON(^)N = 2-(2-nitrosophenyl)pyridine (2a), 10-nitrosobenzo[h]quinoline (2b), 2-(2-nitroso-4-methylphenyl)pyridine, (2c), 2-(2-nitrosophenyl)-5-(trifluoromethyl)pyridine (2d)] and analogues with the 1,4,7-trithiacyclononane ([9]aneS3)/tert-butylisocyanide ligand set, [Ru(ON(^)N)([9]aneS3)(C≡N(t)Bu)](2+) (4a and 4b), have been prepared by insertion of a
Sophie H Dale et al.
Acta crystallographica. Section C, Crystal structure communications, 61(Pt 6), o411-o413 (2005-06-03)
Investigations of the reactivity of the thio-crown [14]aneS(4) (1,4,8,11-tetrathiacyclotetradecane) towards the aminating agent o-mesitylsulfonylhydroxylamine have lead to the crystallization of 1lambda(4),4lambda(4),8lambda(4),11lambda(4)-tetrathiacyclotetradecane-1,4,7,10-tetraylidenetetraaminium tetrakis(2,4,6-trimethylbenzenesulfonate), C10H28N4S(4)4+.4C9H11O3S-. The compound crystallizes in a centrosymmetric space group, with half a formula unit in the asymmetric unit.
Liquid-liquid extraction of metal ions by the thiacrown compound 1, 4, 8, 11-tetrathiacyclotetradecane.
Saito K, et al.
Analytica Chimica Acta, 151, 447-455 (1983)

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