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Merck
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重要文件

247049

Sigma-Aldrich

三丁基膦

mixture of isomers, 97%

同義詞:

P(n-Bu)3, TBP

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About This Item

線性公式:
[CH3(CH2)3]3P
CAS號碼:
分子量::
202.32
Beilstein:
1738261
EC號碼:
MDL號碼:
分類程式碼代碼:
12352128
PubChem物質ID:
NACRES:
NA.22
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蒸汽密度

9 (vs air)

化驗

97%

形狀

liquid

自燃溫度

392 °F

反應適用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Acetylations

reagent type: ligand
reaction type: Addition Reactions

reagent type: ligand
reaction type: Stille Coupling

雜質

<1% TBP oxide
5% TBP isomers

折射率

n20/D 1.462 (lit.)

bp

150 °C/50 mmHg (lit.)

密度

0.81 g/mL at 25 °C (lit.)

官能基

phosphine

SMILES 字串

CCCCP(CCCC)CCCC

InChI

1S/C12H27P/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3

InChI 密鑰

TUQOTMZNTHZOKS-UHFFFAOYSA-N

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應用

1,4-加成催化剂;与二硫化物配合用于醇的硫醚化;酰化催化剂;用于制备活性酯。
与铂(II) 或铂(IV) 一起用于未活化的烯烃的分子间氢胺化反应。[1]

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1A

儲存類別代碼

4.2 - Pyrophoric and self-heating hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

242.6 °F - closed cup

閃點(°C)

117 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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J. Mol. Catal. A: Chem., 271, 145-145 (2007)
E Kaniowska et al.
Journal of chromatography. A, 798(1-2), 27-35 (1998-05-02)
Several human diseases, in particular metabolic disorders, often lead to the accumulation of characteristic metabolites in plasma, urine and cells. The selected diseases of this type include cystinuria and homocystinuria. In the typical laboratory diagnosis of these two diseases, a
Yin-Wei Sun et al.
Organic letters, 12(24), 5664-5667 (2010-11-13)
P(n)Bu(3)-catalyzed cyclization reactions of salicylaldimines and salicylaldehydes with ethyl 2,3-butadienoate gave the corresponding functionalized chromans in moderate to good yields in THF under mild conditions. The new reaction provides a new method for the synthesis of biologically active chroman products.
Cristina-Maria Vâlcu et al.
Proteomics, 6(5), 1599-1605 (2006-02-04)
Protein extraction procedure and the reducing agent content (DTT, dithioerythritol, tributyl phosphine and tris (2-carboxyethyl) phosphine (TCEP)) of the sample and rehydration buffers were optimised for European beech leaves and roots and Norway spruce needles. Optimal extraction was achieved with
Kersti B Nilsson et al.
Dalton transactions (Cambridge, England : 2003), (9)(9), 1312-1319 (2004-07-15)
The coordination chemistry of the solvate complexes of the relatively soft electron-pair acceptor copper(I) has been studied in solution and solid state in seven solvents with strong electron-pair donor properties, liquid ammonia, trimethyl, triethyl, triisopropyl, tri-n-butyl and triphenyl phosphite, and

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Solvothermal synthesis of nanoparticles: applications from nanocircuits and nano-optical circuits to nanomagnetics and biotech.

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