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Merck
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244473

Sigma-Aldrich

4-辛炔

99%

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About This Item

線性公式:
CH3CH2CH2C≡CCH2CH2CH3
CAS號碼:
分子量::
110.20
Beilstein:
1732138
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
eCl@ss:
39010412
PubChem物質ID:
NACRES:
NA.22

蒸汽壓力

35 mmHg ( 37.7 °C)

品質等級

化驗

99%

形狀

liquid

折射率

n20/D 1.425 (lit.)

bp

131-132 °C (lit.)

mp

−103 °C (lit.)

密度

0.751 g/mL at 25 °C (lit.)

SMILES 字串

CCCC#CCCC

InChI

1S/C8H14/c1-3-5-7-8-6-4-2/h3-6H2,1-2H3

InChI 密鑰

GZTNBKQTTZSQNS-UHFFFAOYSA-N

尋找類似的產品? 前往 產品比較指南

一般說明

4-辛炔,也称为二丙基乙炔,可以作为有机合成中的多功能合成砌块。4-辛炔(在四氢呋喃中)的立体选择性半氢化反应动力学已有研究

應用

4-辛炔,一种富电子的二烷基乙炔,可用于合成高度取代的1,3-二烯

訊號詞

Danger

危險分類

Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

84.2 °F - closed cup

閃點(°C)

29 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


分析證明 (COA)

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Cyclopentadienone synthesis by rhodium (I)-catalyzed [3+ 2] cycloaddition reactions of cyclopropenones and alkynes
PA Wender, et al.
Journal of the American Chemical Society, 128, 14814-14815 (2006)
Alexander M Kluwer et al.
Journal of the American Chemical Society, 127(44), 15470-15480 (2005-11-03)
The kinetics of the stereoselective semi-hydrogenation of 4-octyne in THF by the highly active catalyst [Pd{(m,m'-(CF(3))(2)C(6)H(3))-bian}(ma)] (2) (bian = bis(imino)acenaphthene; ma = maleic anhydride) has been investigated. The rate law under hydrogen-rich conditions is described by r = k[4-octyne](0.65)[Pd][H(2)], showing
Chengxiang Zhou et al.
The Journal of organic chemistry, 71(8), 3184-3191 (2006-04-08)
The Pd(II)-catalyzed reaction of arylboronic acids and internal alkynes provides a convenient route to a wide variety of tetrasubstituted olefins. The reaction is conducted in DMSO using molecular O2 as an oxidant in the absence of any base. The reaction
Kelly E Aldrich et al.
Dalton transactions (Cambridge, England : 2003), 48(30), 11352-11360 (2019-07-10)
Highly dehydrated silica gel, SiO2700, gave a material with a total surface hydroxyl density of 0.31 ± 0.05 mmol g-1, 0.9 ± 0.1 Si-OH sites per nm2. Treatment of this material with Ti(NMe2)4 gave Ti(NMe2)3/SiO2700, which is 1.50% ± 0.07
Davide Albani et al.
Nature communications, 9(1), 2634-2634 (2018-07-08)
Ensemble control has been intensively pursued for decades to identify sustainable alternatives to the Lindlar catalyst (PdPb/CaCO3) applied for the partial hydrogenation of alkynes in industrial organic synthesis. Although the geometric and electronic requirements are known, a literature survey illustrates

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