237582

2-苯基亚磺酰基乙酸甲酯

98%

• 線性公式: C₆H₅S(O)CH₂CO₂CH₃
• CAS號碼: 14090-83-6
• 分子量：: 198.24
• Beilstein: 1953383
• EC號碼: 237-936-6
• MDL號碼: MFCD00002087
• 分類程式碼代碼: 12352100
• PubChem物質ID: 24854255
• NACRES: NA.22

屬性

• 化驗: 98%
• 形狀: solid
• bp: 130-131 °C/0.5 mmHg (lit.)
• mp: 52-54 °C (lit.)
• SMILES 字串: COC(=O)CS(=O)c1ccccc1
• InChI: 1S/C9H10O3S/c1-12-9(10)7-13(11)8-5-3-2-4-6-8/h2-6H,7H2,1H3
• InChI 密鑰: JPPXZUDQIXZLIL-UHFFFAOYSA-N

描述

一般說明

Anion of methyl 2-phenylsulfinylacetate undergoes facile alkylative elimination under solid-liquid phase-transfer conditions to afford ring-substituted cinnamates. Methyl 2-phenylsulfinylacetate undergoes condensation reactions with aldehydes to form vinylic sulfoxides.

應用

Anion of methyl 2-phenylsulfinylacetate has been employed in the synthesis of α,β-unsaturated esters.

安全資訊

• 儲存類別代碼: 13 - Non Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 235.4 °F - closed cup
• 閃點（°C）: 113 °C - closed cup
• 個人防護裝備: Eyeshields, Gloves, type N95 (US)