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重要文件

224294

Sigma-Aldrich

硫代磷酰氯

98%

同義詞:

三氯硫磷, 硫代氯化磷酰

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About This Item

線性公式:
PSCl3
CAS號碼:
分子量::
169.40
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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品質等級

化驗

98%

形狀

liquid

折射率

n20/D 1.555 (lit.)

bp

125 °C (lit.)

mp

−35 °C (lit.)

溶解度

benzene: soluble(lit.)
carbon disulfide: soluble(lit.)
carbon tetrachloride: soluble(lit.)
chloroform: soluble(lit.)

密度

1.668 g/mL at 25 °C (lit.)

SMILES 字串

ClP(Cl)(Cl)=S

InChI

1S/Cl3PS/c1-4(2,3)5

InChI 密鑰

WQYSXVGEZYESBR-UHFFFAOYSA-N

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應用

Thiophosphoryl chloride was used in the synthesis of O-ethyl dichlorothiophosphate[1].

象形圖

Skull and crossbonesCorrosion

訊號詞

Danger

危險分類

Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Sarah E Lee et al.
Chembiochem : a European journal of chemical biology, 12(4), 633-640 (2011-02-10)
The elucidation of signalling pathways relies heavily upon the identification of protein kinase substrates. Recent investigations have demonstrated the efficacy of chemical genetics using ATP analogues and modified protein kinases for specific substrate labelling. Here we combine N(6) -(cyclohexyl)ATPγS with
J T Slama et al.
Analytical biochemistry, 209(1), 143-149 (1993-02-15)
Elemental [35S]sulfur was shown to equilibrate with the sulfur of thiophosphoryl chloride when these materials are heated together. This isotopic exchange reaction is the basis of a convenient, microscale synthesis of high specific activity [35S]PSCl3. [35S]Thiophosphoryl chloride is otherwise not
Mohammed D Zidan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 58(8), 1577-1582 (2002-08-09)
A new route has been devised, leading to the production of phosphorus thiotrihalides, SPX3 where X = F, Br and I by an on-line process using phosphorus thiotrichloride, SPCl3 as starting compound gassed over the following heated salts NaF, KBr
D Coloşi-Esca et al.
Journal of applied toxicology : JAT, 4(5), 230-235 (1984-10-01)
The rat acute oral LD50 value of PSCl3 is 750 mg per kg body weight. A rat 90-day oral feeding study at dose levels of 7.5 mg (P1) and 37.5 mg (P5) per kg resulted in increased body weight gain.
Sebastian Golojuch et al.
Bioorganic & medicinal chemistry, 28(13), 115523-115523 (2020-05-05)
Eukaryotic translation initiation factor 4E (eIF4E) is overexpressed in many cancers deregulating translational control of the cell cycle. mRNA 5' cap analogs targeting eIF4E are small molecules with the potential to counteract elevated levels of eIF4E in cancer cells. However

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