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197378

Sigma-Aldrich

苦味酸

moistened with water, ≥98%

同義詞:

2,4,6-三硝基苯酚, PA

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About This Item

線性公式:
(O2N)3C6H2OH
CAS號碼:
分子量::
229.10
顏色索引編號:
10305
Beilstein:
423400
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
暫時無法取得訂價和供貨情況

蒸汽密度

7.9 (vs air)

品質等級

蒸汽壓力

1 mmHg ( 195 °C)

化驗

≥98%

形狀

powder or crystals (with a top layer of Liquid)

包含

≥35% water

expl. lim.

0.01 %

濃度

≥50-<70%

mp

122-123 °C (dried material) (lit.)

溶解度

alcohol: 1 (g/12 mL)(lit.)
benzene: 1 g/10 mL
chloroform: 1 (g/35 mL)
diethyl ether: 1 (g/65 mL)

密度

1.763 g/cm3

官能基

nitro

SMILES 字串

Oc1c(cc(cc1[N+]([O-])=O)[N+]([O-])=O)[N+]([O-])=O

InChI

1S/C6H3N3O7/c10-6-4(8(13)14)1-3(7(11)12)2-5(6)9(15)16/h1-2,10H

InChI 密鑰

OXNIZHLAWKMVMX-UHFFFAOYSA-N

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一般說明

苦味酸(PA,2,4,6-三硝基苯酚)[1]是一种多硝基芳香酸它本质上具有强酸性。由于它易溶于水,因此很容易污染环境。[2]研究人员已经报道过通过三咪唑盐[2]、荧光 [3+2] 自组装纳米级有机笼[3]和罗丹明传感器[4]对 PA 进行灵敏检测。它广泛用于分光光度法和萃取分光光度法测定各种有机化合物。[1]

應用

苦味酸可用于比索洛尔的定量测定[5]
苦味酸已用于制备 Bouin′ 固定液[6]和苦味酸/叠氮化钠/多壁碳纳米管。[7]

象形圖

FlameSkull and crossbones

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Desen. Expl. 1

儲存類別代碼

4.1A - Other explosive hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

302.0 °F - closed cup

閃點(°C)

150 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Two new anthracene-functionalized fluorescent tris-imidazolium salts have been synthesized, characterized, and proven to be selective sensors for picric acid, which is a common constituent of many powerful explosives. Theoretical studies revealed an unusual ground-state electron transfer from picrate anion to
Koushik Acharyya et al.
Chemical communications (Cambridge, England), 50(99), 15788-15791 (2014-11-06)
Dynamic covalent imine chemistry has been utilized to synthesize a fluorescent [3+2] self-assembled nanoscopic organic cage. The fluorescent nature of the reduced analogue of the cage was further exploited for the highly selective detection of the explosive picric acid (PA).
Rhodamine based selective turn-on sensing of picric acid.
Sivaraman G, et al.
Royal Society of Chemistry Advances, 4(58), 30828-30831 (2014)

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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