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重要文件

183644

Sigma-Aldrich

2-溴萘

97%

同義詞:

β-溴萘, β-萘基溴, 2-萘基溴

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About This Item

經驗公式(希爾表示法):
C10H7Br
CAS號碼:
分子量::
207.07
Beilstein:
1858110
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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品質等級

化驗

97%

形狀

solid

雜質

≤3% 1-bromonaphthalene

bp

281-282 °C (lit.)

mp

52-55 °C (lit.)

溶解度

methanol: soluble 50 mg/mL, clear, colorless to yellow

官能基

bromo

SMILES 字串

Brc1ccc2ccccc2c1

InChI

1S/C10H7Br/c11-10-6-5-8-3-1-2-4-9(8)7-10/h1-7H

InChI 密鑰

APSMUYYLXZULMS-UHFFFAOYSA-N

基因資訊

human ... CYP2A6(1548)
mouse ... Cyp2a5(13087)

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一般說明

2-溴萘与氰化亚铜在 N-甲基吡咯烷酮中的反应已有研究[1]。 2-溴萘在甲醇溶剂中的T1→Tn转变的纳秒时间分辨共振拉曼光谱已有研究[2]

應用

在微波辐射下,2-溴萘在水中通过Suzuki交叉偶联反应可用于合成联芳[3]

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Oral - Eye Irrit. 2

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

235.4 °F - closed cup

閃點(°C)

113 °C - closed cup

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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分析證明 (COA)

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Rapid microwave-promoted Suzuki cross coupling reaction in water.
Bai L, et al.
Green Chemistry, 5(5), 615-617 (2003)
Nanosecond time-resolved resonance Raman investigation of the T1→ Tn transition of 2-bromonaphthalene.
Shoute LCT, et al.
Chemical Physics Letters, 290(1), 24-28 (1998)
Notes-A Convenient Synthesis of Water-Soluble Carbodiimides.
Sheehan J, et al.
The Journal of Organic Chemistry, 26(7), 2525-2528 (1961)
J M Shoulder et al.
SAR and QSAR in environmental research, 30(4), 229-245 (2019-03-22)
Persistent organic contaminants in the environment pose an environmental risk due to widespread occurrence and toxic properties. Advanced oxidation processes (AOPs) are treatment methods that have been used to successfully degrade organic contaminants in water, soil, sediments and sludge. Reaction
Isaiah R Speight et al.
Molecules (Basel, Switzerland), 25(3) (2020-02-06)
Owing to the strength of the C-F bond, the 'direct' preparation of Grignard reagents, i.e., the interaction of elemental magnesium with an organic halide, typically in an ethereal solvent, fails for bulk magnesium and organofluorine compounds. Previously described mechanochemical methods

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