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重要文件

119946

Sigma-Aldrich

对氟苯甲酰氯

98%

同義詞:

4-Fluorobenzoic acid chloride, p-Fluorobenzoyl chloride

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About This Item

線性公式:
FC6H4COCl
CAS號碼:
分子量::
158.56
Beilstein:
386215
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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化驗

98%

折射率

n20/D 1.532 (lit.)

bp

82 °C/20 mmHg (lit.)

mp

10-12 °C (lit.)

密度

1.342 g/mL at 25 °C (lit.)

官能基

acyl chloride
fluoro

SMILES 字串

Fc1ccc(cc1)C(Cl)=O

InChI

1S/C7H4ClFO/c8-7(10)5-1-3-6(9)4-2-5/h1-4H

InChI 密鑰

CZKLEJHVLCMVQR-UHFFFAOYSA-N

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一般說明

4-氟苯甲酰氯可与2,6-二甲基萘进行Friedel-Crafts酰化反应得到1,5-(4-氟苯甲酰基)-2,6-二甲基萘。[1]

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

179.6 °F - closed cup

閃點(°C)

82 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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分析證明 (COA)

Lot/Batch Number

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Novel electroactive aromatic polyamide with oligoanilines and azo groups in the backbone: synthesis, characterization and dielectric properties.
He L, et al.
Journal of Polymer Research, 19(1), 1-9 (2012)
Synthesis of [18F] GBR 12909, a dopamine reuptake inhibitor.
Haka MS and Kilbourn MR.
Journal of Labelled Compounds & Radiopharmaceuticals, 28(7), 793-799 (1990)
Synthesis of a novel naphthalene-based poly (arylene ether-ketone) by polycondensation of 1, 5-bis (4-fluorobenzoyl)-2, 6-dimethylnaphthalene with bisphenol A.
Ohno M, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 33(15), 2647-2655 (1995)
Solid-phase Friedel-Crafts acylation on polystyrene resins-synthesis of antiepiletic 1-aryl-3, 5-dihydro-4H-2, 3-benzodiazepin-4-ones.
Bevacqua F, et al.
Tetrahedron Letters, 42(43), 7683-7685 (2001)
New multiblock copolymers of sulfonated poly (4'-phenyl-2, 5-benzophenone) and poly (arylene ether sulfone) for proton exchange membranes. II.
Ghassemi H, et al.
Polymer, 45(17), 5855-5862 (2004)

文章

在 Lewis 酸催化劑的作用下,Friedel-Crafts 醯化作用可透過親電芳香取代鹵素形成單醯化產品。

Friedel-Crafts acylation with Lewis acid catalysts forms monoacylated products via electrophilic aromatic substitution of arenes.

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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