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Merck
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重要文件

115460

Sigma-Aldrich

氟代丙酮

98%

同義詞:

α-Fluoroacetone, 1-Fluoro-2-propanone, Fluoromethyl methyl ketone, Monofluoroacetone

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About This Item

線性公式:
CH3COCH2F
CAS號碼:
分子量::
76.07
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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品質等級

化驗

98%

折射率

n20/D 1.37 (lit.)

bp

75 °C (lit.)

密度

1.054 g/mL at 25 °C (lit.)

官能基

fluoro
ketone

儲存溫度

2-8°C

SMILES 字串

CC(=O)CF

InChI

1S/C3H5FO/c1-3(5)2-4/h2H2,1H3

InChI 密鑰

MSWVMWGCNZQPIA-UHFFFAOYSA-N

一般說明

Aldolizations of fluoroacetone with aldehydes mediated by organocatalyst yield products with high enantioselectivities[1].

應用

Fluoroacetone has been used as a catalyst to study the kinetics of the ketone-catalysed decomposition of peroxymonosulfuric acid (Caro′s acid)[2].

象形圖

FlameSkull and crossbones

訊號詞

Danger

危險分類

Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Flam. Liq. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

44.6 °F - closed cup

閃點(°C)

7 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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Lange A, et al.
J. Chem. Soc. Perkin Trans. II, 7, 1343-1350 (1999)
Y Shiratori et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 56A(9), 1693-1701 (2000-08-22)
The effects of water and heavy water on conformational equilibria of fluoroacetone have been investigated via Raman spectroscopy. Additional Raman bands have been observed in the C-F stretching and the C-C-C symmetric stretching regions for the aqueous solutions. Based on
Xiao-Hua Chen et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 13(2), 689-701 (2006-10-03)
An organocatalyst prepared from (2R,3R)-diethyl 2-amino-3-hydroxysuccinate and L-proline exhibited high regio- and enantioselectivities for the direct aldol reactions of hydroxyacetone and fluoroacetone with aldehydes in aqueous media. It was found that water could be used to control the regioselectivity. The
Kimiyasu Isobe et al.
Applied microbiology and biotechnology, 102(3), 1307-1316 (2017-12-15)
The enzyme responsible for the enantioselective production of (S)-1,1,1-trifluoro-2-propanol ((S)-TFP) from 1,1,1-trifluoroacetone (TFA) has been identified in Ogataea polymorpha NBRC 0799. We purified two carbonyl reductases, OpCRD-A and OpCRD-B from this strain, and revealed their characteristics. Both enzymes were specific
Laura B Favero et al.
The journal of physical chemistry. A, 115(34), 9493-9497 (2011-03-17)
The rotational spectra of five isotopologues of the molecular adduct 1,1,1-trifluoroacetone-water have been assigned using pulsed-jet Fourier-transform microwave spectroscopy. All rotational transitions appear as doublets, due to the internal rotation of the methyl group. Analysis of the tunneling splittings allows

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