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108030

Sigma-Aldrich

3-氯-2-甲基-1-丙烯

technical grade, 90%

同義詞:

β-甲基烯丙基氯

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About This Item

線性公式:
CH2=C(CH3)CH2Cl
CAS號碼:
分子量::
90.55
Beilstein:
878160
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
eCl@ss:
39050134
PubChem物質ID:
NACRES:
NA.22
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等級

technical grade

蒸汽密度

3.12 (vs air)

蒸汽壓力

102 mmHg ( 20 °C)

化驗

90%

自燃溫度

899 °F

包含

~600 ppm BHT as stabilizer

expl. lim.

9.3 %

折射率

n20/D 1.427 (lit.)

bp

71-72 °C (lit.)

mp

−80 °C (lit.)

溶解度

H2O: insoluble
acetone: soluble
chloroform: soluble
diethyl ether: soluble
ethanol: soluble

密度

0.925 g/mL at 20 °C (lit.)

官能基

alkyl halide
chloro

儲存溫度

2-8°C

SMILES 字串

CC(=C)CCl

InChI

1S/C4H7Cl/c1-4(2)3-5/h1,3H2,2H3

InChI 密鑰

OHXAOPZTJOUYKM-UHFFFAOYSA-N

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一般說明

3-Chloro-2-methyl-1-propene is the reactant for the synthesis of cyclobutanone[1].

應用

3-Chloro-2-methyl-1-propene was used to study ring opening polymerization of oxirane derivatives using organotin phosphate condensate[2]. It was used to study cationic polymerization of 3-Chloro-2-methyl-1-propene using using AICI3 and A3IBr, as initiators[3].

訊號詞

Danger

危險分類

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Skin Sens. 1

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

14.0 °F - closed cup

閃點(°C)

-10 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Cyclobutanone from Methylenecyclopropane via Oxaspiropentane.
Salaun JRJC and Conia JM.
Organic Syntheses, 36-36 (1977)
The cationic polymerization of 3-chloro-2-methyl-1-propene.
Marek M, et al.
Makromol. Chem., 187(10), 2337-2344 (1986)
3-Chloro-2-methylpropene.
Report on carcinogens : carcinogen profiles, 10, 57-58 (2004-08-24)
3-Chloro-2-methylpropene.
IARC monographs on the evaluation of carcinogenic risks to humans, 63, 325-333 (1995-01-01)
P C Chan et al.
Cancer research, 46(12 Pt 1), 6349-6352 (1986-12-01)
The carcinogenicity of 3-chloro-2-methylpropene (CMP), a chemical intermediate and insecticide, was studied because of possible human exposure and because of its structural relationship to vinyl chloride and allyl chloride. CMP in corn oil was administered by gavage to groups of

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