推薦產品
反應適用性
reaction type: Grignard Reaction
濃度
0.5 M in THF
密度
0.952 g/mL at 25 °C
SMILES 字串
C\C(C)=C\[Mg]Br
InChI
1S/C4H7.BrH.Mg/c1-4(2)3;;/h1H,2-3H3;1H;/q;;+1/p-1
InChI 密鑰
BKVIQODYSREJQH-UHFFFAOYSA-M
一般說明
2-甲基-1-丙烯基溴化镁是一种杂环有机化合物。它被用于化学合成中的格氏试剂。
應用
用于合成 (2S,3S)-3′-氟代异亮氨酸。
用于研究与芳基甲苯磺酸酯的钯催化偶联反应。
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2
標靶器官
Respiratory system
安全危害
儲存類別代碼
4.3 - Hazardous materials which set free flammable gases upon contact with water
水污染物質分類（WGK）
WGK 3
閃點（°F）
5.0 °F - closed cup
閃點（°C）
-15 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
分析證明 (COA)
輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號，寫有 ‘Lot’或‘Batch’.。
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[Reaction: see text]. Aryl and alkenyl tosylates are easily prepared, inexpensive and, thus, attractive for transition-metal-catalyzed couplings, but their reactivity is low. We report examples of mild, palladium-catalyzed coupling of aryl, alkenyl, and alkyl Grignard reagents with aryl and alkenyl
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The fluorinated amino acid, (2S,3S)-3'-fluoroisoleucine 3, has been synthesised by a route involving stereoselective cuprate or photochemical addition to the compound 4, derived in turn from (2S)-pyroglutamic acid. This provides a reporter group for the hydrophobic amino acid (2S)-isoleucine for
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