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M0925

3α,6α-Mannopentaose

≥85%

Synonym(s):

α-Man-(1→3)(α-Man-[1→6])-α-Man-(1→6)(α-Man-[1→3])-Man

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About This Item

Empirical Formula (Hill Notation):
C30H52O26
CAS Number:
Molecular Weight:
828.72
NACRES:
NA.32
PubChem Substance ID:
UNSPSC Code:
12352200
MDL number:
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Quality Level

assay

≥85%

storage temp.

2-8°C

SMILES string

OC[C@H]1O[C@H](OC[C@H]2O[C@H](OC[C@@H](O)[C@@H](O)[C@H](O[C@H]3O[C@H](CO)[C@@H](O)[C@H](O)[C@@H]3O)[C@H](O)C=O)[C@@H](O)[C@@H](O[C@H]4O[C@H](CO)[C@@H](O)[C@H](O)[C@@H]4O)[C@@H]2O)[C@@H](O)[C@@H](O)[C@@H]1O

InChI

1S/C30H52O26/c31-1-7(35)25(55-29-22(46)19(43)15(39)10(3-33)52-29)13(37)8(36)5-49-28-24(48)26(56-30-23(47)20(44)16(40)11(4-34)53-30)17(41)12(54-28)6-50-27-21(45)18(42)14(38)9(2-32)51-27/h1,7-30,32-48H,2-6H2/t7-,8-,9-,10-,11-,12-,13-,14-,15-,16-,17-,18+,19+,20+,21+,22+,23+,24+,25-,26+,27+,28+,29-,30-/m1/s1

InChI key

YPQGRSSAXDUGEC-LHCUGFEVSA-N

General description

Core structure of some triantennary N-linked oligosaccharides

Application

3α,6α-Mannopentaose has been used:
  • in the modification of six valent osmium complexes with N,N,N′,N′-tetramethylethylenediamine (Os(VI)tem) for voltammetric analysis[1]
  • to study the structure of Burkholderia oklahomensis EO147 agglutinin (BOA)[2]
  • as a commercial isomeric oligosaccharide in matrix-assisted laser desorption/ionization (MALDI) LTQ orbitrap fragmentation studies


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This Item
M105056217B4526
assay

≥85%

assay

≥93% (HPLC)

assay

≥97.0% (HPLC)

assay

≥93%

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

200

storage temp.

2-8°C

storage temp.

−20°C

storage temp.

-

storage temp.

−20°C


wgk

WGK 3

Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



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Articles

N-linked glycosylation, modification, and degradation


Fragmentation of neutral oligosaccharides using the MALDI LTQ Orbitrap
Rohmer M, et al.
International Journal of Mass Spectrometry, 305(2-3), 199-208 (2011)
Mojmír Trefulka et al.
Bioelectrochemistry (Amsterdam, Netherlands), 133, 107494-107494 (2020-03-03)
Compounds containing vicinal diol (glycol) groups, including saccharides, could be modified with sixvalent osmium complexes with nitrogenous ligands, particularly with N,N,N',N'-tetramethylethylenediamine (Os(VI)tem). The modification products are electrochemically active. Here we show that aminosaccharides can also be modified by Os(VI)tem. We
Matthew J Whitley et al.
The FEBS journal, 280(9), 2056-2067 (2013-03-14)
Burkholderia oklahomensis EO147 agglutinin (BOA) is a 29 kDa member of the Oscillatoria agardhii agglutinin (OAA) family of lectins. Members of the OAA family recognize high-mannose glycans, and, by binding to the HIV envelope glycoprotein 120 (gp120), block the virus



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