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Merck

650463

Sigma-Aldrich

二氯甲烷

HPLC Plus, for HPLC, GC, and residue analysis, ≥99.9%, contains 50-150 ppm amylene as stabilizer

别名:

二氯甲烷, 亚甲基氯

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About This Item

经验公式(希尔记法):
CH2Cl2
CAS号:
分子量:
84.93
Beilstein:
1730800
EC 号:
MDL编号:
UNSPSC代码:
12190000
PubChem化学物质编号:
NACRES:
NA.04
价格与库存信息目前不能提供

等级

HPLC Plus

质量水平

蒸汽密度

2.9 (vs air)

蒸汽压

24.45 psi ( 55 °C)
6.83 psi ( 20 °C)

方案

≥99.9%

表单

liquid

自燃温度

1223 °F

包含

50-150 ppm amylene as stabilizer

expl. lim.

22 %

技术

HPLC: suitable
gas chromatography (GC): suitable

杂质

≤ 1.0 ppb Fluorescence (quinine) at 365 nm
≤0.01% water

蒸发残留物

≤0.0001%

卤代烷残留物

≤10 ng/L (as heptachlor epoxide)

折射率

n20/D 1.424 (lit.)

沸点

39.8-40 °C (lit.)

mp

−95 °C (lit.)

密度

1.325 g/mL at 25 °C (lit.)

λ

H2O reference

紫外吸收

λ: 235 nm Amax: 1.0
λ: 240 nm Amax: 0.10
λ: 250 nm Amax: 0.02
λ: 300-400 nm Amax: 0.005

适用性

suitable for residue analysis

SMILES字符串

ClCCl

InChI

1S/CH2Cl2/c2-1-3/h1H2

InChI key

YMWUJEATGCHHMB-UHFFFAOYSA-N

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一般描述

二氯甲烷是一种极性和高挥发性有机化合物(VOC),以其在工业界有多种用途而为人熟知。它可以作为萃取溶剂、金属清洁剂和日常消费品,如粘合剂、鞋抛光喷雾、油漆和粘合剂清除剂。

应用

二氯甲烷可用于以下情况:

  • 使用分散液-液微萃取法(DLLME)从蜂蜜样品中提取新烟碱类化合物
  • 通过液相色谱-串联质谱(LC-MS/MS)分析超声溶剂萃取并净化的烘焙咖啡样品中7种杀虫剂残留
  • 基于DLLME的样品提取物的额外预浓缩,用于通过带有UV检测器的HPLC分析动物源食品中的三种酰氨醇类抗生素
  • 使用HPLC测定两种磺酰脲类除草剂时,去除获取的土壤样品提取物中有机相
  • 开发基于HPLC-安倍检测法分析液态和固态食品样品中三种氨基甲酸酯农药残留时,测试四种萃取溶剂
  • 通过基质固相分散法(MSPD)从蔬菜样品中提取苯菌酮再用HPLC分析

适用于HPLC、分光光度法、环境检测

包装

M-Bottle for Solvents
As a global leader in lab reagents, we are constantly looking for new ways to optimize the safety of our products. The newly developed 4L solvent bottle design features advanced sealing technology that eliminates leaks to make the handling of solvents safer and more convenient than ever before.
See all the new features here!

其他说明

Pure-Pac® II容器需要Micromatic MacroValve耦合器(Z560723)来分配溶剂。
农药残留分析(作为环氧七氯)<10 ng/L

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法律信息

Pure-Pac is a registered trademark of Merck KGaA, Darmstadt, Germany

象形图

Health hazardExclamation mark

警示用语:

Warning

危险分类

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Central nervous system

储存分类代码

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 2

闪点(°F)

does not flash

闪点(°C)

does not flash


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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其他客户在看

Matthew J Walters et al.
Nature protocols, 2(7), 1825-1830 (2007-07-21)
A procedure for the preparation of optically pure alpha-keto-gamma-hydroxy carboxylic acids through stereospecific aldol addition catalyzed by pyruvate aldolases from the Entner-Doudoroff and the DeLey-Doudoroff glycolytic pathways is described. This highly versatile fragment serves as a precursor for a variety
Vitamin B12-mediated hydrodechlorination of dichloromethane by bimetallic Cu/Al particles.
Huang CC, et al.
Chemical Engineering Journal, 273, 413-420 (2015)
Dichloromethane Detection Based on Near-Infrared Absorptive Sensing.
Han JH and Yoon SM
IEEE Journal of Selected Topics in Quantum Electronics, 18(5), 1547-1552 (2012)
Dichloromethane photodegradation using titanium catalysts.
Tanguay JF, et al.
Tanguay JF, et al.
J. Catal., 117(2), 335-347 (1989)
Biodegradation of dichloromethane in an estuarine environment.
Krausova VI, et al.
Hydrobiologia, 559(1), 77-83 (2006)

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Highly accurate HPLC-FLD method for evaluating 15 PAHs in olive oil using Ascentis® Express PAH HPLC column and SPE cleanup, following GB 5009.265-2021.

实验方案

In the present study we demonstrate compliance of silica gel 60 F254 HPTLC plates with USP requirements, and how HPTLC plates are suitable for the Sildenafil citrate-Limit of Imidazole test.

相关内容

In the present study we demonstrate compliance of silica gel 60 F254 HPTLC plates with USP requirements, and how HPTLC plates are suitable for the Sildenafil citrate-Limit of Imidazole test.

The 4L M-Bottle provides safe handling of solvents due to an innovative solvent bottle design with sealing technology to eliminate leaks and reduce risks in solvent dispensing.

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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